Title: Study on the Effect of Solution Acidity on the Green Synthesis of Adipic Acid
Abstract: Oxidation of cyclohexene with H2O2 to adipic acid,in presence of tungsten catalysts,was studied.Effect of presence or absence of organic additives,pH of the initial solution,and pre-addition of acid on the reaction was examt an acid concentration of 0.10 mol/L in initial reaction solution,the optimal yield of adipic acid could be obtained despite absence of organic solvent-,phase transfer agent- and organic additive.Catalysis of acid and rate-determined- step of reaction were discussed in view of reaction route analysis.
Publication Year: 2003
Publication Date: 2003-01-01
Language: en
Type: article
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