Title: Synthesis and Structure of Compound [C(NH_2)_3]_2{[MoO(H_2O)C_2O_4]_2(μ-O)_2}·2H_2O
Abstract: A new compound [C(NH -2) -3 ] -2{ [MoO(H -2O)C -2O -4 ] -2( μ -O) -2}·2H -2O has been prepared and its {crystal } structure has been determined by X-ray diffraction analysis.This compound consists of two edge-shared molybdenum-oxygen octahedra and all the Mo atoms are of charge +5.Mo centers are chelated by oxalates.Carbamidines [C(NH -2) -3 ] ++ act as counter cations and take part in the construction of hydrogen bonds network.The crystal is monoclinic,space group P 2 -1/ c , a 0. 795?6(2)?nm, b =1. 899?6(4)?nm, c =1. 283?2(3)?nm, β = 106. 78(3)°, V =1. 856?8(7)?nm +3, R 1 0. 024?3, ωR -2 0. 067?2.
Publication Year: 2003
Publication Date: 2003-01-01
Language: en
Type: article
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