Title: Synthesis,Crystal Structure and Luminescent Property of Zn(II)Polymer Coordination Based on 6,6′-Dithiodinicotinic Acid
Abstract: A novel zinc coordination polymer {[Zn(cpds)(dpa)]·H2O}n(1)(H2cpds=6,6′-dithiodinicotinic acid,dpa=dipyridin-2-ylamine) has been hydrothermally synthesized and structurally characterized by single-crystal.Complex 1 crystallizes in the triclinic system,space group P1 with a=0.846 7(2),b=1.167 4(3),c=1.226 5(3) nm,α=73.605(3)°,β=78.656(3)°,γ=81.484(3)°,V=1.134 7(5) nm3,Dc=1.850 g·cm-3,Z=2.Single-crystal X-ray analysis reveal that compound 1 contains an infinite 1D chain structure,and the 1D chain was stacked together to form a 3D supramolecular network.Additionally,the fluorescent property and TG analysis for compound 1were also measured and discussed.
Publication Year: 2013
Publication Date: 2013-01-01
Language: en
Type: article
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