Title: Electrostatic Model for Substituent and Solvent Effects on Organic Acids
Abstract: On the basis of experimental results from gas phase and eprevious electrostatic theory, a novel electrostatic model for substituent and solvent effects on organic acids has been constructed. It is found that the present model is consistent with the gas phase limit condition, and that its parameter B has unequivocal physical meaning. B is related to the solvation radius of the functional group and the specific interaction between substituent and solvent. Threrfore, B is considered to be an important parameter for the interaction between solute and solvent.
Publication Year: 1997
Publication Date: 1997-01-01
Language: en
Type: article
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