Title: Crystal Structure of {[Zr(phen)(dpeda)(H_2O)]·H_2O}_(n·)
Abstract: Since the {[Zr(phen)(dpeda)(H2O)]·H2O}n(1)(phen=1,10-phenanthroline, dpeda= 4,4'-Diphenylethylenedicarboxylic acid) has excellent heat resistance and corrosion resistance, it is of great significance in practical applications. In order to study its composition and properties, this paper uses the X-rays to determine the crystal structure, and use the FT-IR Spectroscopy and thermogravimetric analysis the crystal structure. It crystallizes in the monoclinic system, space group P21/n, with lattice parameters a = 10.245(8) ?, b = 18.962(14) ?, c = 15.342(12) ?, β = 106.229(10)°, V = 2862(4) ?3, Z = 4, Mr = 573.70, Dc = 1.332 g/cm3, F(000) = 1168, μ = 0.425 mm-1, S = 1.005.The π-π stacking interactions architected(1) to a supramrolecular structure. Such compounds for the development of polymer provides a new idea. {[Zr(phen)(dpeda)(H2O)]·H2O}n is used as new materials.
Publication Year: 2015
Publication Date: 2015-01-01
Language: en
Type: article
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