Title: Hydrothermal synthesis and crystal structure of a novel complex (C_5N_2H_6)_3(C_5N_2H_7)_3[(PO_4)Mo_(12)O_(36)]·2H_2O
Abstract: The title compound( ( C5N2H6) 3 ( C5N2H7) 3 [( PO4) Mo12 O36]·2H2O,Mr = 2403. 00) is synthesized by hydrothermal reaction. It crystallizes in a mono-clini system with space group P2( 1) /n and unit cell parameters a = 13. 316( 3),b = 22. 414( 5),c = 20. 063( 4),α = 90. 00( 4) °,β = 100. 743 ( 3) °,γ = 90. 00°,V =5883( 2) 3,Z =4,Dc =2. 713 Mg/m3,μ( MoKα) =2. 608mm-1,F000 =4604,R = 0. 0596,wR = 0. 1345,GoF = 1. 042. The structure of title compound consists of a [( PO4) Mo12O36]3 -cluster,which is connected by hydrogen bond through the O atoms with α-Pyridylamine to form a 3-di-mension structure with water molecular and α-Pyridylamine fulfilling.
Publication Year: 2010
Publication Date: 2010-01-01
Language: en
Type: article
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