Title: Assembly of [Mn<sup>II</sup><sub>2</sub>Mn<sup>III</sup><sub>2</sub>]<i>S</i>= 9 Clusters via Azido Bridges: a New Single-Chain Magnet
Abstract: In the present work, we report a new manganese single-chain magnet built from tetranuclear Mn(II)(2)Mn(III)(2) mixed-valence units linked by end-on azido and oximato bridges. All of the intra- and intercluster interactions involve end-on azido bridges, resulting in one ferromagnetic chain of ferromagnetic clusters with local ground state S = 9.
Publication Year: 2011
Publication Date: 2011-03-09
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 44
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