Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W2325190099', 'doi': 'https://doi.org/10.1021/om101081u', 'title': 'Hexacoordinate Silacyclobutane Dichelate Complexes: Structure, Properties, and Ligand Crossover', 'display_name': 'Hexacoordinate Silacyclobutane Dichelate Complexes: Structure, Properties, and Ligand Crossover', 'publication_year': 2011, 'publication_date': '2011-01-10', 'ids': {'openalex': 'https://openalex.org/W2325190099', 'doi': 'https://doi.org/10.1021/om101081u', 'mag': '2325190099'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/om101081u', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4924609', 'display_name': 'Organometallics', 'issn_l': '0276-7333', 'issn': ['0276-7333', '1520-6041'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5034874298', 'display_name': 'S. Yakubovich', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I124227911', 'display_name': 'Ben-Gurion University of the Negev', 'ror': 'https://ror.org/05tkyf982', 'country_code': 'IL', 'type': 'education', 'lineage': ['https://openalex.org/I124227911']}], 'countries': ['IL'], 'is_corresponding': False, 'raw_author_name': 'Shiri Yakubovich', 'raw_affiliation_strings': ['Department of Chemistry, Ben-Gurion University, Beer Sheva 84105, Israel'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Ben-Gurion University, Beer Sheva 84105, Israel', 'institution_ids': ['https://openalex.org/I124227911']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5059566583', 'display_name': 'B. Gostevskii', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I124227911', 'display_name': 'Ben-Gurion University of the Negev', 'ror': 'https://ror.org/05tkyf982', 'country_code': 'IL', 'type': 'education', 'lineage': ['https://openalex.org/I124227911']}], 'countries': ['IL'], 'is_corresponding': False, 'raw_author_name': 'Boris Gostevskii', 'raw_affiliation_strings': ['Department of Chemistry, Ben-Gurion University, Beer Sheva 84105, Israel'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Ben-Gurion University, Beer Sheva 84105, Israel', 'institution_ids': ['https://openalex.org/I124227911']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5068412064', 'display_name': 'I. D. Kalikhman', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I124227911', 'display_name': 'Ben-Gurion University of the Negev', 'ror': 'https://ror.org/05tkyf982', 'country_code': 'IL', 'type': 'education', 'lineage': ['https://openalex.org/I124227911']}], 'countries': ['IL'], 'is_corresponding': False, 'raw_author_name': 'Inna Kalikhman', 'raw_affiliation_strings': ['Department of Chemistry, Ben-Gurion University, Beer Sheva 84105, Israel'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Ben-Gurion University, Beer Sheva 84105, Israel', 'institution_ids': ['https://openalex.org/I124227911']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5075282610', 'display_name': 'Mark Botoshansky', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I174306211', 'display_name': 'Technion – Israel Institute of Technology', 'ror': 'https://ror.org/03qryx823', 'country_code': 'IL', 'type': 'education', 'lineage': ['https://openalex.org/I174306211']}], 'countries': ['IL'], 'is_corresponding': False, 'raw_author_name': 'Mark Botoshansky', 'raw_affiliation_strings': ['Department of Chemistry, Technion−Israel Institute of Technology, Haifa 32000, Israel'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Technion−Israel Institute of Technology, Haifa 32000, Israel', 'institution_ids': ['https://openalex.org/I174306211']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5001374879', 'display_name': 'L. E. Gusel’nikov', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210106238', 'display_name': 'A.V. Topchiev Institute of Petrochemical Synthesis', 'ror': 'https://ror.org/01jgbgc06', 'country_code': 'RU', 'type': 'facility', 'lineage': ['https://openalex.org/I1313323035', 'https://openalex.org/I4210106238', 'https://openalex.org/I4210145551', 'https://openalex.org/I4210163714']}], 'countries': ['RU'], 'is_corresponding': False, 'raw_author_name': 'Leonid E. Gusel’nikov', 'raw_affiliation_strings': ['Institute of Petrochemical Synthesis, RAS, Moscow, Russia'], 'affiliations': [{'raw_affiliation_string': 'Institute of Petrochemical Synthesis, RAS, Moscow, Russia', 'institution_ids': ['https://openalex.org/I4210106238']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5033063592', 'display_name': 'V. A. Pestunovich', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210098151', 'display_name': 'A.E. Favorsky Irkutsk Institute of Chemistry', 'ror': 'https://ror.org/00verxq29', 'country_code': 'RU', 'type': 'facility', 'lineage': ['https://openalex.org/I1313323035', 'https://openalex.org/I4210098151', 'https://openalex.org/I4210145551']}], 'countries': ['RU'], 'is_corresponding': False, 'raw_author_name': 'Vadim A. Pestunovich', 'raw_affiliation_strings': ['Irkutsk Institute of Organic Chemistry, RAS, Siberian Division, Russia'], 'affiliations': [{'raw_affiliation_string': 'Irkutsk Institute of Organic Chemistry, RAS, Siberian Division, Russia', 'institution_ids': ['https://openalex.org/I4210098151']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5030996171', 'display_name': 'Daniel Kost', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I124227911', 'display_name': 'Ben-Gurion University of the Negev', 'ror': 'https://ror.org/05tkyf982', 'country_code': 'IL', 'type': 'education', 'lineage': ['https://openalex.org/I124227911']}], 'countries': ['IL'], 'is_corresponding': False, 'raw_author_name': 'Daniel Kost', 'raw_affiliation_strings': ['Department of Chemistry, Ben-Gurion University, Beer Sheva 84105, Israel'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Ben-Gurion University, Beer Sheva 84105, Israel', 'institution_ids': ['https://openalex.org/I124227911']}]}], 'institution_assertions': [], 'countries_distinct_count': 2, 'institutions_distinct_count': 4, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 1.612, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 21, 'citation_normalized_percentile': {'value': 0.845861, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 90, 'max': 91}, 'biblio': {'volume': '30', 'issue': '3', 'first_page': '405', 'last_page': '413'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10807', 'display_name': 'Synthesis and characterization of novel inorganic/organometallic compounds', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10807', 'display_name': 'Synthesis and characterization of novel inorganic/organometallic compounds', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11441', 'display_name': 'Organoboron and organosilicon chemistry', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10092', 'display_name': 'Organometallic Complex Synthesis and Catalysis', 'score': 0.9987, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/hexacoordinate', 'display_name': 'Hexacoordinate', 'score': 0.99731433}, {'id': 'https://openalex.org/keywords/silicon-tetrachloride', 'display_name': 'Silicon tetrachloride', 'score': 0.6206721}], 'concepts': [{'id': 'https://openalex.org/C2778615665', 'wikidata': 'https://www.wikidata.org/wiki/Q397226', 'display_name': 'Hexacoordinate', 'level': 3, 'score': 0.99731433}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.93598425}, {'id': 'https://openalex.org/C116569031', 'wikidata': 'https://www.wikidata.org/wiki/Q899107', 'display_name': 'Ligand (biochemistry)', 'level': 3, 'score': 0.6323602}, {'id': 'https://openalex.org/C2776412973', 'wikidata': 'https://www.wikidata.org/wiki/Q413709', 'display_name': 'Silicon tetrachloride', 'level': 3, 'score': 0.6206721}, {'id': 'https://openalex.org/C550623735', 'wikidata': 'https://www.wikidata.org/wiki/Q867', 'display_name': 'Germanium', 'level': 3, 'score': 0.5892744}, {'id': 'https://openalex.org/C544956773', 'wikidata': 'https://www.wikidata.org/wiki/Q670', 'display_name': 'Silicon', 'level': 2, 'score': 0.50912946}, {'id': 'https://openalex.org/C2182769', 'wikidata': 'https://www.wikidata.org/wiki/Q62500', 'display_name': 'Ionic bonding', 'level': 3, 'score': 0.450408}, {'id': 'https://openalex.org/C178516000', 'wikidata': 'https://www.wikidata.org/wiki/Q3023362', 'display_name': 'Denticity', 'level': 3, 'score': 0.43492413}, {'id': 'https://openalex.org/C155647269', 'wikidata': 'https://www.wikidata.org/wiki/Q243455', 'display_name': 'Medicinal chemistry', 'level': 1, 'score': 0.41653845}, {'id': 'https://openalex.org/C179104552', 'wikidata': 'https://www.wikidata.org/wiki/Q11165', 'display_name': 'Inorganic chemistry', 'level': 1, 'score': 0.38108888}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.36285943}, {'id': 'https://openalex.org/C8010536', 'wikidata': 'https://www.wikidata.org/wiki/Q160398', 'display_name': 'Crystallography', 'level': 1, 'score': 0.32601845}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.2616641}, {'id': 'https://openalex.org/C115624301', 'wikidata': 'https://www.wikidata.org/wiki/Q895901', 'display_name': 'Crystal structure', 'level': 2, 'score': 0.14317283}, {'id': 'https://openalex.org/C145148216', 'wikidata': 'https://www.wikidata.org/wiki/Q36496', 'display_name': 'Ion', 'level': 2, 'score': 0.12674686}, {'id': 'https://openalex.org/C55493867', 'wikidata': 'https://www.wikidata.org/wiki/Q7094', 'display_name': 'Biochemistry', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C170493617', 'wikidata': 'https://www.wikidata.org/wiki/Q208467', 'display_name': 'Receptor', 'level': 2, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/om101081u', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4924609', 'display_name': 'Organometallics', 'issn_l': '0276-7333', 'issn': ['0276-7333', '1520-6041'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'id': 'https://metadata.un.org/sdg/6', 'display_name': 'Clean water and sanitation', 'score': 0.53}], 'grants': [], 'datasets': ['https://openalex.org/W4398011224', 'https://openalex.org/W4397762852', 'https://openalex.org/W4397583950', 'https://openalex.org/W4397696690', 'https://openalex.org/W4397869900'], 'versions': [], 'referenced_works_count': 25, 'referenced_works': ['https://openalex.org/W1968794854', 'https://openalex.org/W1972203832', 'https://openalex.org/W1983171687', 'https://openalex.org/W1985900127', 'https://openalex.org/W1992217282', 'https://openalex.org/W1993095446', 'https://openalex.org/W2003154516', 'https://openalex.org/W2008770832', 'https://openalex.org/W2010686526', 'https://openalex.org/W2024362301', 'https://openalex.org/W2024672473', 'https://openalex.org/W2034548926', 'https://openalex.org/W2039520214', 'https://openalex.org/W2041849541', 'https://openalex.org/W2045176628', 'https://openalex.org/W2054622351', 'https://openalex.org/W2061917920', 'https://openalex.org/W2070207826', 'https://openalex.org/W2072080183', 'https://openalex.org/W2073940492', 'https://openalex.org/W2074980121', 'https://openalex.org/W2075668437', 'https://openalex.org/W2075722231', 'https://openalex.org/W2141108725', 'https://openalex.org/W2167620957'], 'related_works': ['https://openalex.org/W4252812061', 'https://openalex.org/W4234611027', 'https://openalex.org/W2390661750', 'https://openalex.org/W2325190099', 'https://openalex.org/W2141108725', 'https://openalex.org/W2072152647', 'https://openalex.org/W1994974617', 'https://openalex.org/W1968432633', 'https://openalex.org/W1968004455', 'https://openalex.org/W1521878767'], 'abstract_inverted_index': {'Hexacoordinate': [0], 'dichelate': [1], 'silacyclobutane': [2], 'complexes': [3, 78], 'have': [4, 79], 'been': [5], 'synthesized': [6], 'from': [7, 68], 'dichlorosilacyclobutane': [8], 'and': [9, 22, 32, 56, 101, 110], 'O-trimethylsilylated': [10, 35], 'hydrazides': [11], 'by': [12, 118], 'transsilylation.': [13], 'Like': [14], 'previously': [15], 'reported': [16], 'hexacoordinate': [17, 60, 70], 'silicon': [18, 29, 64, 77], 'complexes,': [19, 71], 'they': [20], 'readily': [21], 'quantitatively': [23], 'undergo': [24], 'ligand': [25, 120], 'exchange': [26, 49, 55, 109, 112], 'with': [27], 'other': [28], 'compounds': [30], '(XSiCl3': [31], 'differently': [33], 'substituted': [34], 'hydrazides),': [36], 'evidence': [37], 'that': [38], 'ionic': [39], 'dissociation': [40], 'does': [41], 'not': [42], 'play': [43], 'a': [44], 'significant': [45], 'role': [46], 'in': [47, 89], 'the': [48, 98], 'mechanism.': [50], 'Germanium': [51], 'tetrachloride': [52, 65], 'causes': [53], 'central-element': [54, 92, 111], 'formation': [57], 'of': [58, 97, 103], 'analogous': [59], 'germanium': [61, 67], 'complexes.': [62], 'Likewise,': [63], 'replaces': [66], 'its': [69], 'obeying': [72], 'certain': [73], 'selectivity': [74], 'constraints.': [75], 'When': [76], 'strongly': [80], 'electron-withdrawing': [81], 'chelate-ring': [82], 'substituents': [83], '(CF3': [84], 'or': [85], 'CH2CN),': [86], 'GeCl4': [87], 'causes,': [88], 'addition': [90, 102], 'to': [91, 115], 'exchange,': [93], 'also': [94], 'oxidative': [95], 'opening': [96], 'four-membered': [99], 'ring': [100], 'two': [104], 'chlorine': [105], 'atoms.': [106], 'Both': [107], 'chelate': [108], 'are': [113], 'shown': [114], 'be': [116], 'dominated': [117], 'monodentate': [119], 'priorities.': [121]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2325190099', 'counts_by_year': [{'year': 2024, 'cited_by_count': 1}, {'year': 2023, 'cited_by_count': 1}, {'year': 2022, 'cited_by_count': 2}, {'year': 2021, 'cited_by_count': 1}, {'year': 2018, 'cited_by_count': 1}, {'year': 2017, 'cited_by_count': 1}, {'year': 2016, 'cited_by_count': 3}, {'year': 2014, 'cited_by_count': 3}, {'year': 2013, 'cited_by_count': 5}, {'year': 2012, 'cited_by_count': 2}], 'updated_date': '2025-01-09T05:03:24.628331', 'created_date': '2016-06-24'}