Title: Cyanide-Bridged Lanthanide−Transition Metal One-Dimensional Arrays {(DMF)<sub>10</sub>Yb<sub>2</sub>[Ni(CN)<sub>4</sub>]<sub>3</sub>}<sub>∞</sub> and {(DMF)<sub>10</sub>Yb<sub>2</sub>[Pt(CN)<sub>4</sub>]<sub>3</sub>}<sub>∞</sub>
Abstract: The one-dimensional arrays {(DMF)10Yb2[Ni(CN)4]3}∞ (1) and {(DMF)10Yb2[Pt(CN)4]3}∞ (2) were prepared from the metathesis reactions of YbCl3 and K2Ni(CN)4 or K2Pt(CN)4 in DMF (DMF = N,N-dimethylformamide). Unlike other one-dimensional structures adopted by complexes of M(CN)42- anions, two unusual array structures were obtained.
Publication Year: 1996
Publication Date: 1996-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 68
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