Publication Information

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'Clean water and sanitation'}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 1, 'referenced_works': ['https://openalex.org/W121418609'], 'related_works': ['https://openalex.org/W4386896511', 'https://openalex.org/W4281655236', 'https://openalex.org/W3012372332', 'https://openalex.org/W2994082062', 'https://openalex.org/W2515577673', 'https://openalex.org/W2349548597', 'https://openalex.org/W2313516441', 'https://openalex.org/W2100711612', 'https://openalex.org/W2062289342', 'https://openalex.org/W1999533757'], 'abstract_inverted_index': {'アルゴン流通下': [0], '(150-200ml/min),': [1], '300°-1100℃の温度範囲で化学量論比の塩化ジルコニウム': [2], '(IV),': [3], '炭素源として活性炭を,': [4], '還元金属としてAl粉末及びMg粉末を用いて,': [5], '効果を調べた.': [6], 'ZnではZrCを合成できなかった.': [7], 'ZrCl4-Al-C系では500°-1000℃でAl3Zrの合金が生成し炭化は800℃以上で進み,': [8], '1100℃でZrCのみとなったが結晶性はよくなかった.': [9], 'また,': [10], '1100℃,': [11, 27], '1h反応でのZrCl4の昇華損失は65.5%に達した.': [12], 'これに対して,': [13], 'ZrCl4-Mg-C系では500℃以上でZrCが生成した.': [14], 'この場合,': [15], '500°-700℃でZrが,': [16], '400°-1000℃でMgCl2が観察された.': [17], 'また原料中の微量の酸素により,': [18], '400℃以上でMgOが800℃以上でZrO2が生成した.': [19], 'そこでMgの混合比を化学量論比の1.5倍にしたところ,': [20], 'ZrO2は認められず,': [21], '逆に,': [22], 'ZrC及びMgO量が増加した.': [23], '反応生成物を1N塩酸で洗浄処理したところ,': [24], 'MgO及びMgCl2は除去され,': [25], '800℃以上でZrC単相となった.': [26], '1h反応で得られたZrCは微粉末': [28], '(粒径0.1-0.3μm)': [29], 'で,': [30], '格子定数a=4.686Å,': [31], '結晶子径は159Åであった.': [32], 'またこのときのZrCl4の昇華損失は0.2%であった.': [33], '以上のことから,': [34], '還元金属としてMgが有効であることが分った.': [35]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2313516441', 'counts_by_year': [], 'updated_date': '2024-12-09T01:07:39.966332', 'created_date': '2016-06-24'}