Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W2263677676', 'doi': 'https://doi.org/10.1021/acs.jpcc.5b09312', 'title': 'Mobility of the 2-Methylimidazolate Linkers in ZIF-8 Probed by <sup>2</sup>H NMR: Saloon Doors for the Guests', 'display_name': 'Mobility of the 2-Methylimidazolate Linkers in ZIF-8 Probed by <sup>2</sup>H NMR: Saloon Doors for the Guests', 'publication_year': 2015, 'publication_date': '2015-11-19', 'ids': {'openalex': 'https://openalex.org/W2263677676', 'doi': 'https://doi.org/10.1021/acs.jpcc.5b09312', 'mag': '2263677676'}, 'language': 'en', 'primary_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1021/acs.jpcc.5b09312', 'pdf_url': 'https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.5b09312', 'source': {'id': 'https://openalex.org/S95739953', 'display_name': 'The Journal of Physical Chemistry C', 'issn_l': '1932-7447', 'issn': ['1932-7447', '1932-7455'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': 'publisher-specific-oa', 'license_id': 'https://openalex.org/licenses/publisher-specific-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': True, 'oa_status': 'bronze', 'oa_url': 'https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.5b09312', 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5048587728', 'display_name': 'Daniil I. Kolokolov', 'orcid': 'https://orcid.org/0000-0002-1434-095X'}, 'institutions': [{'id': 'https://openalex.org/I188973947', 'display_name': 'Novosibirsk State University', 'ror': 'https://ror.org/04t2ss102', 'country_code': 'RU', 'type': 'education', 'lineage': ['https://openalex.org/I188973947']}, {'id': 'https://openalex.org/I4210150028', 'display_name': "Institut de Recherches sur la Catalyse et l'Environnement de Lyon", 'ror': 'https://ror.org/04fy20a51', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I100532134', 'https://openalex.org/I1294671590', 'https://openalex.org/I203339264', 'https://openalex.org/I4210128300', 'https://openalex.org/I4210150028']}, {'id': 'https://openalex.org/I4210094231', 'display_name': 'Boreskov Institute of Catalysis', 'ror': 'https://ror.org/00kftxm09', 'country_code': 'RU', 'type': 'facility', 'lineage': ['https://openalex.org/I1313323035', 'https://openalex.org/I4210094231', 'https://openalex.org/I4210145551']}], 'countries': ['FR', 'RU'], 'is_corresponding': False, 'raw_author_name': 'Daniil I. Kolokolov', 'raw_affiliation_strings': ['Boreskov Institute\rof Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia', 'Department\rof Physical Chemistry, Faculty of Natural Sciences, Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090, Russia', "Institut de recherches sur la catalyse et l'environnement de Lyon"], 'affiliations': [{'raw_affiliation_string': 'Department\rof Physical Chemistry, Faculty of Natural Sciences, Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090, Russia', 'institution_ids': ['https://openalex.org/I188973947']}, {'raw_affiliation_string': "Institut de recherches sur la catalyse et l'environnement de Lyon", 'institution_ids': ['https://openalex.org/I4210150028']}, {'raw_affiliation_string': 'Boreskov Institute\rof Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia', 'institution_ids': ['https://openalex.org/I4210094231']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5045633595', 'display_name': 'Alexander G. Stepanov', 'orcid': 'https://orcid.org/0000-0003-2754-5273'}, 'institutions': [{'id': 'https://openalex.org/I188973947', 'display_name': 'Novosibirsk State University', 'ror': 'https://ror.org/04t2ss102', 'country_code': 'RU', 'type': 'education', 'lineage': ['https://openalex.org/I188973947']}, {'id': 'https://openalex.org/I4210094231', 'display_name': 'Boreskov Institute of Catalysis', 'ror': 'https://ror.org/00kftxm09', 'country_code': 'RU', 'type': 'facility', 'lineage': ['https://openalex.org/I1313323035', 'https://openalex.org/I4210094231', 'https://openalex.org/I4210145551']}], 'countries': ['RU'], 'is_corresponding': False, 'raw_author_name': 'Alexander G. Stepanov', 'raw_affiliation_strings': ['Boreskov Institute\rof Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia', 'Department\rof Physical Chemistry, Faculty of Natural Sciences, Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090, Russia'], 'affiliations': [{'raw_affiliation_string': 'Department\rof Physical Chemistry, Faculty of Natural Sciences, Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090, Russia', 'institution_ids': ['https://openalex.org/I188973947']}, {'raw_affiliation_string': 'Boreskov Institute\rof Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia', 'institution_ids': ['https://openalex.org/I4210094231']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5007031715', 'display_name': 'Hervé Jobic', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210150028', 'display_name': "Institut de Recherches sur la Catalyse et l'Environnement de Lyon", 'ror': 'https://ror.org/04fy20a51', 'country_code': 'FR', 'type': 'facility', 'lineage': ['https://openalex.org/I100532134', 'https://openalex.org/I1294671590', 'https://openalex.org/I203339264', 'https://openalex.org/I4210128300', 'https://openalex.org/I4210150028']}, {'id': 'https://openalex.org/I1294671590', 'display_name': 'Centre National de la Recherche Scientifique', 'ror': 'https://ror.org/02feahw73', 'country_code': 'FR', 'type': 'government', 'lineage': ['https://openalex.org/I1294671590']}, {'id': 'https://openalex.org/I203339264', 'display_name': 'Université de Lyon', 'ror': 'https://ror.org/01rk35k63', 'country_code': 'FR', 'type': 'education', 'lineage': ['https://openalex.org/I203339264']}], 'countries': ['FR'], 'is_corresponding': False, 'raw_author_name': 'Hervé Jobic', 'raw_affiliation_strings': ['Institut de Recherches\rsur la Catalyse et l’Environnement de Lyon, CNRS, Université\rde Lyon, 2, Avenue Albert Einstein, 69626 Villeurbanne, France'], 'affiliations': [{'raw_affiliation_string': 'Institut de Recherches\rsur la Catalyse et l’Environnement de Lyon, CNRS, Université\rde Lyon, 2, Avenue Albert Einstein, 69626 Villeurbanne, France', 'institution_ids': ['https://openalex.org/I4210150028', 'https://openalex.org/I1294671590', 'https://openalex.org/I203339264']}]}], 'institution_assertions': [], 'countries_distinct_count': 2, 'institutions_distinct_count': 5, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 4.017, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 104, 'citation_normalized_percentile': {'value': 0.856324, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 98, 'max': 99}, 'biblio': {'volume': '119', 'issue': '49', 'first_page': '27512', 'last_page': '27520'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10096', 'display_name': 'Metal-Organic Frameworks: Synthesis and Applications', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10096', 'display_name': 'Metal-Organic Frameworks: Synthesis and Applications', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10612', 'display_name': 'Magnetism in coordination complexes', 'score': 0.9959, 'subfield': {'id': 'https://openalex.org/subfields/2504', 'display_name': 'Electronic, Optical and Magnetic Materials'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10798', 'display_name': 'Crystallography and molecular interactions', 'score': 0.9927, 'subfield': {'id': 'https://openalex.org/subfields/1606', 'display_name': 'Physical and Theoretical Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/linker', 'display_name': 'Linker', 'score': 0.56771195}], 'concepts': [{'id': 'https://openalex.org/C2777691172', 'wikidata': 'https://www.wikidata.org/wiki/Q2270', 'display_name': 'Benzene', 'level': 2, 'score': 0.5993441}, {'id': 'https://openalex.org/C32909587', 'wikidata': 'https://www.wikidata.org/wiki/Q11369', 'display_name': 'Molecule', 'level': 2, 'score': 0.59659195}, {'id': 'https://openalex.org/C2780557392', 'wikidata': 'https://www.wikidata.org/wiki/Q523796', 'display_name': 'Linker', 'level': 2, 'score': 0.56771195}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.5322905}, {'id': 'https://openalex.org/C8010536', 'wikidata': 'https://www.wikidata.org/wiki/Q160398', 'display_name': 'Crystallography', 'level': 1, 'score': 0.4549576}, {'id': 'https://openalex.org/C192562407', 'wikidata': 'https://www.wikidata.org/wiki/Q228736', 'display_name': 'Materials science', 'level': 0, 'score': 0.34941113}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.076165944}, {'id': 'https://openalex.org/C41008148', 'wikidata': 'https://www.wikidata.org/wiki/Q21198', 'display_name': 'Computer science', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C111919701', 'wikidata': 'https://www.wikidata.org/wiki/Q9135', 'display_name': 'Operating system', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 3, 'locations': [{'is_oa': True, 'landing_page_url': 'https://doi.org/10.1021/acs.jpcc.5b09312', 'pdf_url': 'https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.5b09312', 'source': {'id': 'https://openalex.org/S95739953', 'display_name': 'The Journal of Physical Chemistry C', 'issn_l': '1932-7447', 'issn': ['1932-7447', '1932-7455'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': 'publisher-specific-oa', 'license_id': 'https://openalex.org/licenses/publisher-specific-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': False, 'landing_page_url': 'https://hal.science/hal-01277437', 'pdf_url': None, 'source': None, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://hal.archives-ouvertes.fr/hal-01277437', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306402512', 'display_name': 'HAL (Le Centre pour la Communication Scientifique Directe)', 'issn_l': None, 'issn': None, 'is_oa': True, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1294671590', 'host_organization_name': 'Centre National de la Recherche Scientifique', 'host_organization_lineage': ['https://openalex.org/I1294671590'], 'host_organization_lineage_names': ['Centre National de la Recherche Scientifique'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1021/acs.jpcc.5b09312', 'pdf_url': 'https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.5b09312', 'source': {'id': 'https://openalex.org/S95739953', 'display_name': 'The Journal of Physical Chemistry C', 'issn_l': '1932-7447', 'issn': ['1932-7447', '1932-7455'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': 'publisher-specific-oa', 'license_id': 'https://openalex.org/licenses/publisher-specific-oa', 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'sustainable_development_goals': [], 'grants': [{'funder': 'https://openalex.org/F4320321079', 'funder_display_name': 'Russian Foundation for Basic Research', 'award_id': '14-03-91333'}], 'datasets': [], 'versions': [], 'referenced_works_count': 50, 'referenced_works': ['https://openalex.org/W1967466085', 'https://openalex.org/W1969002373', 'https://openalex.org/W1977418233', 'https://openalex.org/W1988706956', 'https://openalex.org/W1992419329', 'https://openalex.org/W2001037711', 'https://openalex.org/W2007353272', 'https://openalex.org/W2008346096', 'https://openalex.org/W2010674190', 'https://openalex.org/W2018572475', 'https://openalex.org/W2019696371', 'https://openalex.org/W2019744287', 'https://openalex.org/W2020385319', 'https://openalex.org/W2031521238', 'https://openalex.org/W203643116', 'https://openalex.org/W2039141427', 'https://openalex.org/W2041844627', 'https://openalex.org/W2051955453', 'https://openalex.org/W2051958965', 'https://openalex.org/W2067554041', 'https://openalex.org/W2070053149', 'https://openalex.org/W2074835605', 'https://openalex.org/W2079778708', 'https://openalex.org/W2081325459', 'https://openalex.org/W2089405538', 'https://openalex.org/W2093770411', 'https://openalex.org/W2096839611', 'https://openalex.org/W2109849656', 'https://openalex.org/W2114784691', 'https://openalex.org/W2124925409', 'https://openalex.org/W2139482086', 'https://openalex.org/W2147397013', 'https://openalex.org/W2162560681', 'https://openalex.org/W2163535530', 'https://openalex.org/W2316124489', 'https://openalex.org/W2316651128', 'https://openalex.org/W2319611377', 'https://openalex.org/W2321829382', 'https://openalex.org/W2324486822', 'https://openalex.org/W2326341713', 'https://openalex.org/W2328546001', 'https://openalex.org/W2329225027', 'https://openalex.org/W2330890671', 'https://openalex.org/W2330955531', 'https://openalex.org/W2332471611', 'https://openalex.org/W2512550757', 'https://openalex.org/W2618816381', 'https://openalex.org/W3004024615', 'https://openalex.org/W4231889015', 'https://openalex.org/W430316297'], 'related_works': ['https://openalex.org/W4247375799', 'https://openalex.org/W3144105522', 'https://openalex.org/W2920176150', 'https://openalex.org/W2899084033', 'https://openalex.org/W2372005294', 'https://openalex.org/W2091436431', 'https://openalex.org/W2080971378', 'https://openalex.org/W2073620476', 'https://openalex.org/W2048490996', 'https://openalex.org/W2027377285'], 'abstract_inverted_index': {'ZIF-8': [0, 55, 107, 135, 197], 'is': [1, 23, 69, 114, 192], 'one': [2], 'of': [3, 74, 96, 105, 119, 138, 147, 205, 219, 229], 'the': [4, 46, 49, 72, 75, 83, 89, 102, 106, 117, 136, 167, 182, 196, 203, 206, 217, 220, 226, 230], 'most': [5], 'interesting': [6], 'metal–organic': [7], 'frameworks': [8], 'due': [9], 'to': [10, 59, 116, 170, 209, 235], 'its': [11], 'high': [12, 160], 'stability': [13], 'and': [14, 111, 159], 'unique': [15], 'capabilities': [16], 'for': [17, 43], 'hydrocarbons': [18], 'separation.': [19], 'Its': [20], 'porous': [21], 'network': [22], 'formed': [24], 'by': [25, 31, 94], 'large': [26, 63, 212], 'almost': [27], 'spherical': [28], 'cavities': [29, 56], 'interconnected': [30], 'very': [32, 109, 152, 211], 'narrow': [33], 'windows,': [34], '∼3.4': [35], 'Å,': [36], 'which': [37], 'should': [38], 'be': [39], 'too': [40], 'small': [41], 'even': [42, 61], 'methane.': [44], 'At': [45], 'same': [47], 'time': [48], 'direct': [50, 193], 'experimental': [51], 'observations': [52], 'show': [53, 100], 'that': [54, 87, 101, 195], 'are': [57, 108], 'able': [58], 'host': [60], 'such': [62], 'molecules': [64], 'as': [65], 'benzene.': [66], 'This': [67, 191], 'effect': [68], 'associated': [70], 'with': [71, 124, 151, 175, 181], 'flexibility': [73], 'cavity': [76], 'widows,': [77], 'arising': [78], 'from': [79], 'dynamical': [80], 'freedom': [81], 'on': [82, 129], '2-methylimidazole': [84], '(2-mIM)': [85], 'linkers': [86, 104, 168, 198, 231], 'form': [88], 'framework.': [90], 'In': [91, 122], 'this': [92], 'work,': [93], 'means': [95], '2H': [97], 'NMR': [98], 'we': [99], '2-mIM': [103, 139], 'mobile': [110], 'their': [112], 'mobility': [113], 'sensitive': [115], 'presence': [118], 'benzene': [120, 215], 'guest.': [121], 'contrast': [123], 'other': [125], 'known': [126], 'MOFs': [127], 'based': [128], 'linearly': [130], 'bonded': [131], 'carboxylates,': [132], 'in': [133], 'guest-free': [134], 'plane': [137], 'linker': [140], 'exhibits': [141], 'two-site': [142, 183], 'flips': [143, 184], 'within': [144], 'a': [145], 'sector': [146], '2φf': [148], '=': [149, 186], '34°': [150], 'low': [153], 'activation': [154], 'barrier': [155, 228], '(1.5': [156], 'kJ': [157, 237], 'mol–1)': [158], 'rates': [161], '(∼1012': [162], 's–1).': [163], 'Above': [164], '380': [165], 'K': [166], 'begin': [169], 'demonstrate': [171], 'additional': [172], 'fast': [173], 'librations': [174], 'gradually': [176], 'increasing': [177, 202], 'amplitudes': [178], 'γlib': [179], 'comparable': [180], '(γlib': [185], '±17°': [187], 'above': [188], '560': [189], 'K).': [190], 'evidence': [194], 'twist': [199], 'notably,': [200], 'thus': [201], 'aperture': [204], 'windows': [207], 'sufficiently': [208], 'fit': [210], 'molecules.': [213], 'Upon': [214], 'loading,': [216], 'geometry': [218], 'observed': [221], 'motions': [222], 'remains': [223], 'similar': [224], 'but': [225], 'potential': [227], 'flipping': [232], 'rises': [233], 'up': [234], '9': [236], 'mol–1.': [238]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2263677676', 'counts_by_year': [{'year': 2024, 'cited_by_count': 9}, {'year': 2023, 'cited_by_count': 13}, {'year': 2022, 'cited_by_count': 9}, {'year': 2021, 'cited_by_count': 14}, {'year': 2020, 'cited_by_count': 10}, {'year': 2019, 'cited_by_count': 12}, {'year': 2018, 'cited_by_count': 15}, {'year': 2017, 'cited_by_count': 14}, {'year': 2016, 'cited_by_count': 7}], 'updated_date': '2024-12-08T22:09:31.823175', 'created_date': '2016-06-24'}