Title: Organocatalytic Highly Enantioselective α‐Arylation of β‐Ketoesters
Abstract: Angewandte ChemieVolume 119, Issue 29 p. 5611-5615 Zuschrift Organocatalytic Highly Enantioselective α-Arylation of β-Ketoesters† José Alemán Dr., José Alemán Dr. Danish National Research Foundation, Center for Catalysis Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark, Fax: (+45) 8919-6199Search for more papers by this authorBo Richter, Bo Richter Danish National Research Foundation, Center for Catalysis Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark, Fax: (+45) 8919-6199Search for more papers by this authorKarl Anker Jørgensen Prof. Dr., Karl Anker Jørgensen Prof. Dr. [email protected] Danish National Research Foundation, Center for Catalysis Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark, Fax: (+45) 8919-6199Search for more papers by this author José Alemán Dr., José Alemán Dr. Danish National Research Foundation, Center for Catalysis Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark, Fax: (+45) 8919-6199Search for more papers by this authorBo Richter, Bo Richter Danish National Research Foundation, Center for Catalysis Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark, Fax: (+45) 8919-6199Search for more papers by this authorKarl Anker Jørgensen Prof. Dr., Karl Anker Jørgensen Prof. Dr. [email protected] Danish National Research Foundation, Center for Catalysis Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark, Fax: (+45) 8919-6199Search for more papers by this author First published: 04 July 2007 https://doi.org/10.1002/ange.200701009Citations: 29 † This work was made possible by a grant from the Danish National Research Foundation. J.A. thanks the Ministerio de Educación y Ciencia of Spain for a postdoctoral fellowship. We thank Dr. Jacob Overgaard for performing X-ray analysis, Dr. Kim Frisch for conversations about quinone systems, and Dr. Peter Dinér for help in DFT calculations. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Von Chinonen zu komplexen Verbindungen: Die Umsetzung von β-Ketoestern mit Chinonen ermöglicht α-Arylierungen, vor allem wenn der α-Arylring elektronenschiebende Gruppen enthält. Die Reaktion lässt sich enantioselektiv durchführen, wenn Chinaalkaloide als Organokatalysatoren eingesetzt werden, und macht komplexe polycyclische und chirale Spiroverbindungen zugänglich. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z701009_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume119, Issue29July 16, 2007Pages 5611-5615 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. RelatedInformation