Publication Information

{'id': 'https://openalex.org/W2166295771', 'doi': 'https://doi.org/10.1063/1.1723621', 'title': 'Thermodynamics of High Polymer Solutions', 'display_name': 'Thermodynamics of High Polymer Solutions', 'publication_year': 1942, 'publication_date': '1942-01-01', 'ids': {'openalex': 'https://openalex.org/W2166295771', 'doi': 'https://doi.org/10.1063/1.1723621', 'mag': '2166295771'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1063/1.1723621', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S77047749', 'display_name': 'The Journal of Chemical Physics', 'issn_l': '0021-9606', 'issn': ['0021-9606', '1089-7690', '1520-9032'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320257', 'host_organization_name': 'American Institute of Physics', 'host_organization_lineage': ['https://openalex.org/P4310320257'], 'host_organization_lineage_names': ['American Institute of Physics'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5058114693', 'display_name': 'Paul J. Flory', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I4210107489', 'display_name': 'American Standard (United States)', 'ror': 'https://ror.org/013b0rk29', 'country_code': 'US', 'type': 'company', 'lineage': ['https://openalex.org/I4210107489']}], 'countries': ['US'], 'is_corresponding': True, 'raw_author_name': 'Paul J. Flory', 'raw_affiliation_strings': ['Esso Laboratories of the Standard Oil Development Company, Chemical Division, Linden, New Jersey'], 'affiliations': [{'raw_affiliation_string': 'Esso Laboratories of the Standard Oil Development Company, Chemical Division, Linden, New Jersey', 'institution_ids': ['https://openalex.org/I4210107489']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': ['https://openalex.org/A5058114693'], 'corresponding_institution_ids': ['https://openalex.org/I4210107489'], 'apc_list': {'value': 3500, 'currency': 'USD', 'value_usd': 3500, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 34.196, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 4026, 'citation_normalized_percentile': {'value': 0.997491, 'is_in_top_1_percent': True, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 99, 'max': 100}, 'biblio': {'volume': '10', 'issue': '1', 'first_page': '51', 'last_page': '61'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10402', 'display_name': 'Phase Equilibria and Thermodynamics', 'score': 0.9947, 'subfield': {'id': 'https://openalex.org/subfields/2204', 'display_name': 'Biomedical Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10402', 'display_name': 'Phase Equilibria and Thermodynamics', 'score': 0.9947, 'subfield': {'id': 'https://openalex.org/subfields/2204', 'display_name': 'Biomedical Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10474', 'display_name': 'Material Dynamics and Properties', 'score': 0.9936, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11379', 'display_name': 'Rheology and Fluid Dynamics Studies', 'score': 0.9893, 'subfield': {'id': 'https://openalex.org/subfields/1507', 'display_name': 'Fluid Flow and Transfer Processes'}, 'field': {'id': 'https://openalex.org/fields/15', 'display_name': 'Chemical Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/miscibility', 'display_name': 'Miscibility', 'score': 0.7304027}, {'id': 'https://openalex.org/keywords/molality', 'display_name': 'Molality', 'score': 0.6520052}, {'id': 'https://openalex.org/keywords/entropy-of-mixing', 'display_name': 'Entropy of mixing', 'score': 0.5901916}, {'id': 'https://openalex.org/keywords/excluded-volume', 'display_name': 'Excluded volume', 'score': 0.4165271}], 'concepts': [{'id': 'https://openalex.org/C97355855', 'wikidata': 'https://www.wikidata.org/wiki/Q11473', 'display_name': 'Thermodynamics', 'level': 1, 'score': 0.75831354}, {'id': 'https://openalex.org/C521977710', 'wikidata': 'https://www.wikidata.org/wiki/Q81163', 'display_name': 'Polymer', 'level': 2, 'score': 0.73918235}, {'id': 'https://openalex.org/C110884469', 'wikidata': 'https://www.wikidata.org/wiki/Q906367', 'display_name': 'Miscibility', 'level': 3, 'score': 0.7304027}, {'id': 'https://openalex.org/C16946580', 'wikidata': 'https://www.wikidata.org/wiki/Q172623', 'display_name': 'Molality', 'level': 3, 'score': 0.6520052}, {'id': 'https://openalex.org/C32909587', 'wikidata': 'https://www.wikidata.org/wiki/Q11369', 'display_name': 'Molecule', 'level': 2, 'score': 0.6083923}, {'id': 'https://openalex.org/C126680732', 'wikidata': 'https://www.wikidata.org/wiki/Q1000031', 'display_name': 'Entropy of mixing', 'level': 3, 'score': 0.5901916}, {'id': 'https://openalex.org/C124589349', 'wikidata': 'https://www.wikidata.org/wiki/Q3726376', 'display_name': 'Configuration entropy', 'level': 2, 'score': 0.5471727}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.52575976}, {'id': 'https://openalex.org/C2780471494', 'wikidata': 'https://www.wikidata.org/wiki/Q146505', 'display_name': 'Solvent', 'level': 2, 'score': 0.5164078}, {'id': 'https://openalex.org/C106301342', 'wikidata': 'https://www.wikidata.org/wiki/Q4117933', 'display_name': 'Entropy (arrow of time)', 'level': 2, 'score': 0.51441747}, {'id': 'https://openalex.org/C138777275', 'wikidata': 'https://www.wikidata.org/wiki/Q6884054', 'display_name': 'Mixing (physics)', 'level': 2, 'score': 0.46492815}, {'id': 'https://openalex.org/C16309883', 'wikidata': 'https://www.wikidata.org/wiki/Q5419669', 'display_name': 'Excluded volume', 'level': 3, 'score': 0.4165271}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.22194809}, {'id': 'https://openalex.org/C184651966', 'wikidata': 'https://www.wikidata.org/wiki/Q906356', 'display_name': 'Aqueous solution', 'level': 2, 'score': 0.2084592}, {'id': 'https://openalex.org/C147789679', 'wikidata': 'https://www.wikidata.org/wiki/Q11372', 'display_name': 'Physical chemistry', 'level': 1, 'score': 0.2002638}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.12716466}, {'id': 'https://openalex.org/C3288061', 'wikidata': 'https://www.wikidata.org/wiki/Q161064', 'display_name': 'Enthalpy', 'level': 2, 'score': 0.117654145}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.09177673}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1063/1.1723621', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S77047749', 'display_name': 'The Journal of Chemical Physics', 'issn_l': '0021-9606', 'issn': ['0021-9606', '1089-7690', '1520-9032'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320257', 'host_organization_name': 'American Institute of Physics', 'host_organization_lineage': ['https://openalex.org/P4310320257'], 'host_organization_lineage_names': ['American Institute of Physics'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 23, 'referenced_works': ['https://openalex.org/W1974229973', 'https://openalex.org/W1979873550', 'https://openalex.org/W1991595566', 'https://openalex.org/W1992154440', 'https://openalex.org/W1992781280', 'https://openalex.org/W1994874504', 'https://openalex.org/W1996904154', 'https://openalex.org/W2008237051', 'https://openalex.org/W2009969331', 'https://openalex.org/W2035873257', 'https://openalex.org/W2037542092', 'https://openalex.org/W2041278780', 'https://openalex.org/W2055009642', 'https://openalex.org/W2058504160', 'https://openalex.org/W2086739819', 'https://openalex.org/W2106519774', 'https://openalex.org/W2128094334', 'https://openalex.org/W2136346280', 'https://openalex.org/W2150665984', 'https://openalex.org/W2164521967', 'https://openalex.org/W2335529424', 'https://openalex.org/W2335655142', 'https://openalex.org/W2775636289'], 'related_works': ['https://openalex.org/W4281253244', 'https://openalex.org/W2623139398', 'https://openalex.org/W2535468054', 'https://openalex.org/W2113647827', 'https://openalex.org/W2076122139', 'https://openalex.org/W2053536972', 'https://openalex.org/W2032935307', 'https://openalex.org/W2005362103', 'https://openalex.org/W2000465641', 'https://openalex.org/W1964689465'], 'abstract_inverted_index': {'A': [0], 'statistical': [1], 'mechanical': [2], 'treatment': [3], 'of': [4, 15, 34, 41, 50, 52, 79, 88, 119, 141, 150, 152, 162, 165, 176, 204, 226, 231], 'high': [5, 142], 'polymer': [6, 58, 90, 143, 157], 'solutions': [7, 144], 'has': [8], 'been': [9, 108, 199], 'carried': [10], 'out': [11], 'on': [12], 'the': [13, 27, 32, 35, 48, 77, 89, 99, 114, 117, 120, 132, 138, 163, 186, 202, 215, 240, 243], 'basis': [14], 'an': [16, 253], 'idealized': [17], 'model,': [18], 'originally': [19], 'proposed': [20], 'by': [21, 83, 110], 'Meyer,': [22], 'which': [23, 135], 'is': [24, 45, 76, 94, 123, 158], 'analogous': [25], 'to': [26, 98, 160, 239, 245], 'one': [28], 'ordinarily': [29], 'assumed': [30], 'in': [31, 96, 201, 210, 234, 251], 'derivation': [33], "``ideal''": [36, 146], 'solution': [37], 'laws': [38], 'for': [39, 47, 102, 137, 193, 218, 242], 'molecules': [40, 59, 81], 'equal': [42], 'size.': [43], 'There': [44], 'obtained': [46], 'entropy': [49, 149], 'mixing': [51, 177], 'n': [53], 'solvent': [54, 80], 'and': [55, 69, 74, 185], 'N': [56], 'linear': [57, 156], '(originally': [60], 'disoriented),': [61], 'ΔS=−k[(n/β)': [62], 'ln': [63, 65], 'v1+N': [64], 'v2]': [66], 'where': [67], 'v1': [68], 'v2': [70], 'are': [71, 183, 188, 237], 'volume': [72, 111], 'fractions': [73, 106], 'β': [75], 'number': [78], 'replaceable': [82], 'a': [84, 153, 173, 223, 247], 'freely': [85], 'orienting': [86], 'segment': [87], 'chain.': [91], 'This': [92], 'expression': [93, 101, 126], 'similar': [95], 'form': [97], 'classical': [100, 133], 'equal-sized': [103], 'molecules,': [104], 'mole': [105], 'having': [107], 'replaced': [109], 'fractions.': [112], 'When': [113], 'disparity': [115], 'between': [116], 'sizes': [118], 'two': [121], 'components': [122], 'great,': [124], 'this': [125], 'gives': [127], 'entropies': [128], 'differing': [129], 'widely': [130], 'from': [131, 145], 'values,': [134], 'accounts': [136], 'large': [139], 'deviations': [140], 'behavior.': [147], 'The': [148, 207], 'disorientation': [151], 'perfectly': [154], 'arranged': [155], 'found': [159], 'be': [161], 'order': [164], 'R': [166], 'cal.': [167], 'per': [168], 'chain': [169], 'segment.': [170], 'After': [171], 'introducing': [172], 'suitable': [174], 'heat': [175], 'term,': [178], 'partial': [179, 205, 219], 'molal': [180], 'free': [181], 'energies': [182], 'computed,': [184], 'calculations': [187], 'compared': [189], 'with': [190, 212], 'experimental': [191], 'data': [192], 'all': [194], 'concentrations.': [195], 'Phase': [196], 'equilibria': [197], 'have': [198], 'calculated': [200], 'region': [203], 'miscibility.': [206], 'theory': [208], 'predicts,': [209], 'agreement': [211], 'experiment,': [213], 'that': [214], 'critical': [216], 'composition': [217], 'miscibility': [220], 'lies': [221], 'at': [222], 'low': [224], 'concentration': [225], 'polymer.': [227], 'Low': [228], 'intrinsic': [229], 'viscosities': [230], 'polymers': [232], 'dissolved': [233], 'poor': [235], 'solvents': [236], 'attributed': [238], 'tendency': [241], 'molecule': [244], 'assume': [246], 'more': [248], 'compact': [249], 'configuration': [250], 'such': [252], 'environment.': [254]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2166295771', 'counts_by_year': [{'year': 2024, 'cited_by_count': 223}, {'year': 2023, 'cited_by_count': 204}, {'year': 2022, 'cited_by_count': 194}, {'year': 2021, 'cited_by_count': 184}, {'year': 2020, 'cited_by_count': 198}, {'year': 2019, 'cited_by_count': 163}, {'year': 2018, 'cited_by_count': 169}, {'year': 2017, 'cited_by_count': 140}, {'year': 2016, 'cited_by_count': 125}, {'year': 2015, 'cited_by_count': 149}, {'year': 2014, 'cited_by_count': 111}, {'year': 2013, 'cited_by_count': 106}, {'year': 2012, 'cited_by_count': 92}], 'updated_date': '2025-01-12T09:48:01.889309', 'created_date': '2016-06-24'}