Title: Gas‐Phase Reduction of Oxides of Nitrogen with CO Catalyzed by Atomic Transition‐Metal Cations
Abstract: Angewandte Chemie International EditionVolume 42, Issue 40 p. 4923-4927 Communication Gas-Phase Reduction of Oxides of Nitrogen with CO Catalyzed by Atomic Transition-Metal Cations† Voislav Blagojevic, Voislav Blagojevic Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorMichael J. Y. Jarvis, Michael J. Y. Jarvis Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorEric Flaim, Eric Flaim Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorGregory K. Koyanagi, Gregory K. Koyanagi Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorVitali V. Lavrov, Vitali V. Lavrov Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorDiethard K. Bohme Prof., Diethard K. Bohme Prof. [email protected] Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this author Voislav Blagojevic, Voislav Blagojevic Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorMichael J. Y. Jarvis, Michael J. Y. Jarvis Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorEric Flaim, Eric Flaim Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorGregory K. Koyanagi, Gregory K. Koyanagi Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorVitali V. Lavrov, Vitali V. Lavrov Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this authorDiethard K. Bohme Prof., Diethard K. Bohme Prof. [email protected] Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada, Fax: (+1) 416-736-5936Search for more papers by this author First published: 15 October 2003 https://doi.org/10.1002/anie.200351628Citations: 60 † Support for this research by the Natural Sciences and Engineering Research Council of Canada is greatly appreciated. Also, we acknowledge support from the National Research Council, the Natural Science and Engineering Research Council, and MDS SCIEX in the form of a Research Partnership grant. As holder of a Canada Research Chair in Physical Chemistry, D.K.B. thanks the contributions of the Canada Research Chair Program to this research. We also thank Dr. I. Kretzschmar for helpful discussions. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract A novel catalytic role for transition-metal cations in the homogeneous conversion of the nitrogen oxides NO2, NO, or N2O and CO into N2 and CO2 is demonstrated by thermodynamic and kinetic studies of gas-phase reactions of 29 transition-metal cations and some of their oxides (see scheme). Fe+, Os+, and Ir+ ions are shown to be most effective. The chemistry identified may have practical applications in new designs of catalytic converters. Citing Literature Volume42, Issue40October 20, 2003Pages 4923-4927 RelatedInformation
Publication Year: 2003
Publication Date: 2003-10-15
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 64
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