Title: ℝPM‐1: A Recyclable Nanoporous Material Suitable for Ship‐In‐Bottle Synthesis and Large Hydrocarbon Sorption
Abstract: Angewandte Chemie International EditionVolume 42, Issue 5 p. 542-546 Communication ℝPM-1: A Recyclable Nanoporous Material Suitable for Ship-In-Bottle Synthesis and Large Hydrocarbon Sorption† Long Pan Dr., Long Pan Dr. Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA, Fax: (+1) 732-445-5312Search for more papers by this authorHaiming Liu Dr., Haiming Liu Dr. Department of Chemical Engineering, University of Pennsylvania, Philadelphia, PA 19104, USASearch for more papers by this authorXuegong Lei Dr., Xuegong Lei Dr. Department of Chemistry, Columbia University, New York, NY 10027, USASearch for more papers by this authorXiaoying Huang, Xiaoying Huang Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA, Fax: (+1) 732-445-5312Search for more papers by this authorDavid H. Olson Prof., David H. Olson Prof. Department of Chemical Engineering, University of Pennsylvania, Philadelphia, PA 19104, USASearch for more papers by this authorNicholas J. Turro Prof., Nicholas J. Turro Prof. Department of Chemistry, Columbia University, New York, NY 10027, USASearch for more papers by this authorJing Li Prof., Jing Li Prof. [email protected] Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA, Fax: (+1) 732-445-5312Search for more papers by this author Long Pan Dr., Long Pan Dr. Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA, Fax: (+1) 732-445-5312Search for more papers by this authorHaiming Liu Dr., Haiming Liu Dr. Department of Chemical Engineering, University of Pennsylvania, Philadelphia, PA 19104, USASearch for more papers by this authorXuegong Lei Dr., Xuegong Lei Dr. Department of Chemistry, Columbia University, New York, NY 10027, USASearch for more papers by this authorXiaoying Huang, Xiaoying Huang Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA, Fax: (+1) 732-445-5312Search for more papers by this authorDavid H. Olson Prof., David H. Olson Prof. Department of Chemical Engineering, University of Pennsylvania, Philadelphia, PA 19104, USASearch for more papers by this authorNicholas J. Turro Prof., Nicholas J. Turro Prof. Department of Chemistry, Columbia University, New York, NY 10027, USASearch for more papers by this authorJing Li Prof., Jing Li Prof. [email protected] Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA, Fax: (+1) 732-445-5312Search for more papers by this author First published: 30 January 2003 https://doi.org/10.1002/anie.200390156Citations: 441 † The Rutgers University team is grateful to the National Science Foundation for its generous support (MDR-0094732). This work was supported in part by the MRSEC Program of the National Science Foundation under Award Number DMR-9809687, and by the National Science Foundation and the Department of Energy under Grant No. NSF CHE9810367 to the Environmental Molecular Sciences Institute at Columbia University. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Narrow windows and large supercavities comprise the novel nanoporous coordination organometallic structure ℝPM-1, which has a two-fold interpenetrating 3D network containing unique open channels (see picture). ℝPM-1 exhibits a high sorption capacity for large hydrocarbons and superior size/shape selectivity for the photolysis of ortho-methyl dibenzyl ketone (o-MeDBK; 100 % cage effect). A completely reversible structural transformation takes place between ℝPM-1 and a nonporous 1D compound, which allows a full recovery of the o-MeDBK derived products (100 % mass balance). Citing Literature Volume42, Issue5February 3, 2003Pages 542-546 RelatedInformation
Publication Year: 2003
Publication Date: 2003-01-30
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 457
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