Title: Crystallization in a Mixture of Solvents by Using a Crystal Modifier: Morphology Control in the Synthesis of Highly Monodisperse CaCO<sub>3</sub> Microspheres
Abstract: Angewandte Chemie International EditionVolume 45, Issue 24 p. 3977-3981 Communication Crystallization in a Mixture of Solvents by Using a Crystal Modifier: Morphology Control in the Synthesis of Highly Monodisperse CaCO3 Microspheres† Xiao-Hui Guo, Xiao-Hui Guo Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, School of Chemistry and Materials, University of Science and Technology of China, Hefei 230026, P.R. China, Fax: (+86) 551-360-3040Search for more papers by this authorShu-Hong Yu Prof. Dr., Shu-Hong Yu Prof. Dr. [email protected] Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, School of Chemistry and Materials, University of Science and Technology of China, Hefei 230026, P.R. China, Fax: (+86) 551-360-3040Search for more papers by this authorGuo-Bing Cai, Guo-Bing Cai Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, School of Chemistry and Materials, University of Science and Technology of China, Hefei 230026, P.R. China, Fax: (+86) 551-360-3040Search for more papers by this author Xiao-Hui Guo, Xiao-Hui Guo Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, School of Chemistry and Materials, University of Science and Technology of China, Hefei 230026, P.R. China, Fax: (+86) 551-360-3040Search for more papers by this authorShu-Hong Yu Prof. Dr., Shu-Hong Yu Prof. Dr. [email protected] Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, School of Chemistry and Materials, University of Science and Technology of China, Hefei 230026, P.R. China, Fax: (+86) 551-360-3040Search for more papers by this authorGuo-Bing Cai, Guo-Bing Cai Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, School of Chemistry and Materials, University of Science and Technology of China, Hefei 230026, P.R. China, Fax: (+86) 551-360-3040Search for more papers by this author First published: 01 June 2006 https://doi.org/10.1002/anie.200600029Citations: 141 † We acknowledge the special funding support from the Centurial Program of the Chinese Academy of Sciences, the National Natural Science Foundation of China (NSFC, Nos. 20325104, 20321101, 50372065) and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, the Specialized Research Fund for the Doctoral Program (SRFDP) of Higher Education State Education Ministry, the Partner Group of the Chinese Academy of Sciences, and the Max Planck Society. We genuinely thank PD. Dr. habil. H. Cölfen and Prof. Dr. M. Antonietti for donating the block copolymers and for the long-standing and enjoyable collaboration in the area of biomimetic mineralization. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract It's under control: In the presence of an artificial double-hydrophilic block copolymer, poly(ethylene glycol)-b-poly(L-glutamic acid), highly monodisperse vaterite microspheres crystallize from a mixture of N,N-dimethylformamide and water (see picture). 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