Title: Effizienter photooxidativer Abbau von organischen Verbindungen in Gegenwart von Eisentetrasulfophthalocyanin unter Bestrahlung mit sichtbarem Licht
Abstract: Angewandte ChemieVolume 113, Issue 16 p. 3103-3105 Zuschrift Effizienter photooxidativer Abbau von organischen Verbindungen in Gegenwart von Eisentetrasulfophthalocyanin unter Bestrahlung mit sichtbarem Licht† Xia Tao, Xia Tao Laboratory of Photochemistry, Center for Molecular Sciences Institute of Chemistry, The Chinese Academy of Sciences Beijing 100080, China, Fax: (+86) 10-6487-9375Search for more papers by this authorWanhong Ma, Wanhong Ma Laboratory of Photochemistry, Center for Molecular Sciences Institute of Chemistry, The Chinese Academy of Sciences Beijing 100080, China, Fax: (+86) 10-6487-9375Search for more papers by this authorTianyong Zhang, Tianyong Zhang Laboratory of Photochemistry, Center for Molecular Sciences Institute of Chemistry, The Chinese Academy of Sciences Beijing 100080, China, Fax: (+86) 10-6487-9375Search for more papers by this authorJincai Zhao Prof., Jincai Zhao Prof. [email protected] Laboratory of Photochemistry, Center for Molecular Sciences Institute of Chemistry, The Chinese Academy of Sciences Beijing 100080, China, Fax: (+86) 10-6487-9375Search for more papers by this author Xia Tao, Xia Tao Laboratory of Photochemistry, Center for Molecular Sciences Institute of Chemistry, The Chinese Academy of Sciences Beijing 100080, China, Fax: (+86) 10-6487-9375Search for more papers by this authorWanhong Ma, Wanhong Ma Laboratory of Photochemistry, Center for Molecular Sciences Institute of Chemistry, The Chinese Academy of Sciences Beijing 100080, China, Fax: (+86) 10-6487-9375Search for more papers by this authorTianyong Zhang, Tianyong Zhang Laboratory of Photochemistry, Center for Molecular Sciences Institute of Chemistry, The Chinese Academy of Sciences Beijing 100080, China, Fax: (+86) 10-6487-9375Search for more papers by this authorJincai Zhao Prof., Jincai Zhao Prof. [email protected] Laboratory of Photochemistry, Center for Molecular Sciences Institute of Chemistry, The Chinese Academy of Sciences Beijing 100080, China, Fax: (+86) 10-6487-9375Search for more papers by this author First published: 15 August 2001 https://doi.org/10.1002/1521-3757(20010817)113:16<3103::AID-ANGE3103>3.0.CO;2-MCitations: 19 † Diese Arbeit wurde finanziell vom NSFC (Förder-Nr. 29877026, 4001161947, 29725715 und 20077027) und vom CAS unterstützt. Die Autoren danken Dr. Huiyong Zhu, University of Queensland, Australien, für hilfreiche Diskussionen. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract Sichtbares Licht beschleunigt den oxidativen Abbau von organischen Verbindungen wie Rhodamin B und Salicylsäure, die als Testverbindungen für organische Schadstoffe dienen. Die Abbaureaktionen verlaufen wesentlich schneller als dieselben Prozesse unter Lichtausschluss. Der Mechanismus beruht auf der lichtinduzierten Erzeugung von HO.-Radikalen, die mit den Schadstoffen zu den Abbauprodukten reagieren. References 1 Google Scholar 1a M. R. Hoffmann, S. T. Martin, W. Choi, D. W. Bahnemann, Chem. Rev. 1995, 95, 69–96; 10.1021/cr00033a004 CASWeb of Science®Google Scholar 1b T. Wu, G. Liu, J. Zhao, H. Hidaka, N. Serpone, J. Phys. Chem. 1999, 103, 4862–4867; CASWeb of Science®Google Scholar 1c T. Wu, T. Lin, J. Zhao, H. Hidaka, N. Serpone, Environ. Sci. Technol. 1999, 33, 1379–1387. 10.1021/es980923i CASWeb of Science®Google Scholar 2 Google Scholar 2a O. Legrini, E. Oliveros, A. M. Braun, Chem. Rev. 1993, 93, 671–698; 10.1021/cr00018a003 CASWeb of Science®Google Scholar 2b K. Wu, T. Zhang, J. Zhao, H. Hidaka, Chem. Lett. 1998, 857. 10.1246/cl.1998.857 CASWeb of Science®Google Scholar 3 Google Scholar 3a A. Sorokin, B. Meunier, J. Chem. Soc. Chem. Commun. 1994, 1799–1800; 10.1039/c39940001799 CASWeb of Science®Google Scholar 3b A. Sorokin, J. L. Séris, B. Meunier, Science 1995, 268, 1163–1166; 10.1126/science.268.5214.1163 CASPubMedWeb of Science®Google Scholar 3c A. Sorokin, S. D. Suzzoni-Dezard, D. Póullain, J. P. Noël, B. Meunier, J. Am. Chem. Soc. 1996, 118, 7410–7411. 10.1021/ja960177m CASWeb of Science®Google Scholar 4 A. Hadasch, A. Sorokin, A. Rabion, B. Meunier, New J. Chem. 1998, 45–51. 10.1039/a706741k CASWeb of Science®Google Scholar 5 Der Abbau des gesamten organisch gebundenen Kohlenstoffs (TOC) wurde mittels eines TOC-Analysators (Appllo 9000) untersucht. Die Lösung enthielt zu Beginn der Reaktion 30 μM RhB, 25 μM [Fe(PcS)] und 0.05 M H2O2. Während der Reaktion wurde keine Zersetzung von [Fe(PcS)] beobachtet (laut UV/Vis-Spektropskopie und HPLC-Analyse), was darauf hinweist, dass die Entfernung des TOC durch den Abbau des RhB begründet ist. Google Scholar 6 J. Zhao, T. Wu, K. Wu, K. Oikawa, H. Hidaka, N. Serpone, Environ. Sci. Technol. 1998, 32, 2394–2400. 10.1021/es9707926 CASWeb of Science®Google Scholar 7 A. Maldotti, C. Bartocci, G. Varani, A. Molinari, Inorg. Chem. 1996, 35, 1126–1131. 10.1021/ic950386s CASPubMedWeb of Science®Google Scholar 8 G. V. Buxton, C. L. Greenstock, W. P. Helman, A. B. Ross, J. Phys. Chem. Ref. Data 1988, 17, 513–886. 10.1063/1.555805 CASWeb of Science®Google Scholar 9 C. Walling, Acc. Chem. Res. 1975, 8, 125–131. 10.1021/ar50088a003 CASWeb of Science®Google Scholar 10 E. E. Wegner, A. W. Adamson, J. Am. Chem. Soc. 1966, 5, 394–403. 10.1021/ja00955a003 Google Scholar 11 Google Scholar 11a Y. Ito, J. Chem. Soc. Chem. Commun. 1991, 622–624; 10.1039/c39910000622 CASPubMedWeb of Science®Google Scholar 11b F. Adar, M. Gouterman, S. Aronowitz, J. Phys. Chem. 1976, 80, 2184–2197; 10.1021/j100561a010 CASWeb of Science®Google Scholar 11c W. A. Eaton, R. M. Hochstrasser, J. Chem. Phys. 1968, 49, 985–995; 10.1063/1.1670263 CASPubMedWeb of Science®Google Scholar 11d M. E. Balmer, B. Sulzberger, Environ. Sci. Technol. 1999, 33, 2418–2424. 10.1021/es9808705 CASWeb of Science®Google Scholar 12 M. F. Sisemore, J. N. Burstyn, J. S. Valentine, Angew. Chem. 1996, 108, 195–196; 10.1002/ange.19961080213 Google ScholarAngew. Chem. Int. Ed. Engl. 1996, 35, 206–208. 10.1002/anie.199602061 CASWeb of Science®Google Scholar Citing Literature Volume113, Issue16August 17, 2001Pages 3103-3105 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. ReferencesRelatedInformation
Publication Year: 2001
Publication Date: 2001-08-17
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 21
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot