Title: Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)
Abstract: Phosphinoamide ligands have been utilized to link a Co(I) center to a Nb or Ta imido fragment. The resulting heterobimetallic complexes, ICo(Ph(2)PN(i)Pr)(3)M=N(t)Bu, have weakened dative metal-metal interactions as a result of the strongly donating imido ligand. These complexes can be reduced by 2 electrons to generate dinitrogen-bound complexes.
Publication Year: 2012
Publication Date: 2012-01-01
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 23
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