Title: A New Atropisomeric Molecular Structure for Efficient Enantiodifferentiation
Abstract: Enantioselective clathrate formation and sorption is possible with the enantiomers of the novel atropisomer 1. Racemic 1 is easily accessible from 2,2′-dibromophenyl and fluorenone; the (S)-(+) enantiomer can be obtained pure with (−)-fenchone on formation of the sparingly soluble inclusion complex. Other potential applications are envisaged for these atropisomers in analysis and in asymmetric synthesis.
Publication Year: 1993
Publication Date: 1993-04-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 37
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