Title: Synthesis of AB Ring Model System of Taxol <i>via</i> Allylation of 8-Membered Ring Compound and Intramolecular Aldol Condensation
Abstract: Abstract 1-t-Butyldimethylsiloxy-8,11,11-trimethylbicyclo[5.3.1]undec-7-en-9-one (2) has been synthesized via intramolecular aldol condensation of the precursor 3 by combined use of lithium diisopropylamide (LDA) and CeCl3. The dicarbonyl compound 3 was prepared by allylation of 8-membered ring ketone 6b.
Publication Year: 1995
Publication Date: 1995-03-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 19
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