Title: Anodic Oxidation on a Boron‐Doped Diamond Electrode Mediated by Methoxy Radicals
Abstract: Angewandte Chemie International EditionVolume 51, Issue 22 p. 5443-5446 Communication Anodic Oxidation on a Boron-Doped Diamond Electrode Mediated by Methoxy Radicals† Takenori Sumi, Takenori Sumi Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorDr. Tsuyoshi Saitoh, Dr. Tsuyoshi Saitoh Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorKeisuke Natsui, Keisuke Natsui Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorDr. Takashi Yamamoto, Dr. Takashi Yamamoto Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorProf. Dr. Mahito Atobe, Prof. Dr. Mahito Atobe Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, Tokiwadai 79-5, Hodogaya-ku, 240-8501 Yokohama (Japan)Search for more papers by this authorProf. Dr. Yasuaki Einaga, Corresponding Author Prof. Dr. Yasuaki Einaga [email protected] Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan) JST, CREST, Hiyoshi 3-14-1, 223-8522 Yokohama (Japan) Yasuaki Einaga, Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan) Shigeru Nishiyama, Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorProf. Dr. Shigeru Nishiyama, Corresponding Author Prof. Dr. Shigeru Nishiyama [email protected] Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan) Yasuaki Einaga, Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan) Shigeru Nishiyama, Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this author Takenori Sumi, Takenori Sumi Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorDr. Tsuyoshi Saitoh, Dr. Tsuyoshi Saitoh Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorKeisuke Natsui, Keisuke Natsui Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorDr. Takashi Yamamoto, Dr. Takashi Yamamoto Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorProf. Dr. Mahito Atobe, Prof. Dr. Mahito Atobe Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, Tokiwadai 79-5, Hodogaya-ku, 240-8501 Yokohama (Japan)Search for more papers by this authorProf. Dr. Yasuaki Einaga, Corresponding Author Prof. Dr. Yasuaki Einaga [email protected] Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan) JST, CREST, Hiyoshi 3-14-1, 223-8522 Yokohama (Japan) Yasuaki Einaga, Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan) Shigeru Nishiyama, Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this authorProf. Dr. Shigeru Nishiyama, Corresponding Author Prof. Dr. Shigeru Nishiyama [email protected] Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan) Yasuaki Einaga, Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan) Shigeru Nishiyama, Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, 223-8522 Yokohama (Japan)Search for more papers by this author First published: 18 April 2012 https://doi.org/10.1002/anie.201200878Citations: 83 † Supported by a grant from the Science Research Promotion Fund from the Promotion and Mutual Aid Corporation for Private Schools of Japan from MEXT. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron-doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarin A, was accomplished by the BDD-mediated anodic oxidation protocol (see picture). Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201200878_sm_miscellaneous_information.pdf132.8 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue22May 29, 2012Pages 5443-5446 RelatedInformation
Publication Year: 2012
Publication Date: 2012-04-18
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 96
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