Pentacarba-arachno-tridecaalane (AlMe)8(CCH2Ph)5H with an Al8C5 Skeleton—The First Polyhedral Carbaalane

Name: Work Video:
Duration: 3 min 30 s
Description: Hydroalumination of an aluminum alkynide led to the formation of a polyhedral carbaalane as the first example of a new class of aluminum derivatives analogous to carbaboranes. A pentacarbatridecaalane was obtained, which has an Al8C5 skeleton and which, owing to the number of electrons in the cluster, belongs to the arachno-type group of compounds (see structure).
Werner Uhl; Frank Breher
{'id': 'https://openalex.org/W2141103276', 'doi': 'https://doi.org/10.1002/(sici)1521-3773(19990517)38:10<1477::aid-anie1477>3.0.co;2-s', 'title': 'Pentacarba-arachno-tridecaalane (AlMe)8(CCH2Ph)5H with an Al8C5 Skeleton—The First Polyhedral Carbaalane', 'display_name': 'Pentacarba-arachno-tridecaalane (AlMe)8(CCH2Ph)5H with an Al8C5 Skeleton—The First Polyhedral Carbaalane', 'publication_year': 1999, 'publication_date': '1999-05-17', 'ids': {'openalex': 'https://openalex.org/W2141103276', 'doi': 'https://doi.org/10.1002/(sici)1521-3773(19990517)38:10<1477::aid-anie1477>3.0.co;2-s', 'mag': '2141103276', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/29711579'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/(sici)1521-3773(19990517)38:10<1477::aid-anie1477>3.0.co;2-s', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S67393510', 'display_name': 'Angewandte Chemie International Edition', 'issn_l': '1433-7851', 'issn': ['1433-7851', '1521-3773'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5032754495', 'display_name': 'Werner Uhl', 'orcid': 'https://orcid.org/0000-0002-7178-5517'}, 'institutions': [{'id': 'https://openalex.org/I129877168', 'display_name': 'Carl von Ossietzky Universität Oldenburg', 'ror': 'https://ror.org/033n9gh91', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I129877168']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Werner Uhl', 'raw_affiliation_strings': ['Fachbereich Chemie der Universität, Postfach 2503, D-26111 Oldenburg (Germany), Fax: (+49)\u2009441-798-3329.'], 'affiliations': [{'raw_affiliation_string': 'Fachbereich Chemie der Universität, Postfach 2503, D-26111 Oldenburg (Germany), Fax: (+49)\u2009441-798-3329.', 'institution_ids': ['https://openalex.org/I129877168']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5013590724', 'display_name': 'Frank Breher', 'orcid': 'https://orcid.org/0000-0002-6615-1712'}, 'institutions': [{'id': 'https://openalex.org/I129877168', 'display_name': 'Carl von Ossietzky Universität Oldenburg', 'ror': 'https://ror.org/033n9gh91', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I129877168']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Frank Breher', 'raw_affiliation_strings': ['Fachbereich Chemie der Universität, Postfach 2503, D-26111 Oldenburg (Germany), Fax: (+49)\u2009441-798-3329.'], 'affiliations': [{'raw_affiliation_string': 'Fachbereich Chemie der Universität, Postfach 2503, D-26111 Oldenburg (Germany), Fax: (+49)\u2009441-798-3329.', 'institution_ids': ['https://openalex.org/I129877168']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 5250, 'currency': 'USD', 'value_usd': 5250, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 2.548, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 49, 'citation_normalized_percentile': {'value': 0.895454, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 91, 'max': 92}, 'biblio': {'volume': '38', 'issue': '10', 'first_page': '1477', 'last_page': '1479'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11441', 'display_name': 'Organoboron and organosilicon chemistry', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11441', 'display_name': 'Organoboron and organosilicon chemistry', 'score': 0.9999, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11341', 'display_name': 'Boron and Carbon Nanomaterials Research', 'score': 0.9995, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10807', 'display_name': 'Synthesis and characterization of novel inorganic/organometallic compounds', 'score': 0.9994, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/skeleton', 'display_name': 'Skeleton (computer programming)', 'score': 0.6830083}], 'concepts': [{'id': 'https://openalex.org/C18969341', 'wikidata': 'https://www.wikidata.org/wiki/Q1169129', 'display_name': 'Skeleton (computer programming)', 'level': 2, 'score': 0.6830083}, {'id': 'https://openalex.org/C164866538', 'wikidata': 'https://www.wikidata.org/wiki/Q367351', 'display_name': 'Cluster (spacecraft)', 'level': 2, 'score': 0.5925245}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.4547746}, {'id': 'https://openalex.org/C513153333', 'wikidata': 'https://www.wikidata.org/wiki/Q663', 'display_name': 'Aluminium', 'level': 2, 'score': 0.42340168}, {'id': 'https://openalex.org/C8010536', 'wikidata': 'https://www.wikidata.org/wiki/Q160398', 'display_name': 'Crystallography', 'level': 1, 'score': 0.4055115}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.37263295}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.14001337}, {'id': 'https://openalex.org/C41008148', 'wikidata': 'https://www.wikidata.org/wiki/Q21198', 'display_name': 'Computer science', 'level': 0, 'score': 0.10420439}, {'id': 'https://openalex.org/C199360897', 'wikidata': 'https://www.wikidata.org/wiki/Q9143', 'display_name': 'Programming language', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 2, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/(sici)1521-3773(19990517)38:10<1477::aid-anie1477>3.0.co;2-s', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S67393510', 'display_name': 'Angewandte Chemie International Edition', 'issn_l': '1433-7851', 'issn': ['1433-7851', '1521-3773'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/29711579', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': ['https://openalex.org/W4397146748'], 'versions': [], 'referenced_works_count': 0, 'referenced_works': [], 'related_works': ['https://openalex.org/W4253358700', 'https://openalex.org/W4242396160', 'https://openalex.org/W4237955578', 'https://openalex.org/W3139863978', 'https://openalex.org/W2953562271', 'https://openalex.org/W2464530384', 'https://openalex.org/W2334655667', 'https://openalex.org/W2105938841', 'https://openalex.org/W2014897006', 'https://openalex.org/W1756135943'], 'abstract_inverted_index': {'Hydroalumination': [0], 'of': [1, 9, 17, 21, 42, 52], 'an': [2, 33], 'aluminum': [3, 22], 'alkynide': [4], 'led': [5], 'to': [6, 25, 39, 48], 'the': [7, 14, 40, 45, 49], 'formation': [8], 'a': [10, 18], 'polyhedral': [11], 'carbaalane': [12], 'as': [13], 'first': [15], 'example': [16], 'new': [19], 'class': [20], 'derivatives': [23], 'analogous': [24], 'carbaboranes.': [26], 'A': [27], 'pentacarbatridecaalane': [28], 'was': [29], 'obtained,': [30], 'which': [31], 'has': [32], 'Al8C5': [34], 'skeleton': [35], 'and': [36], 'which,': [37], 'owing': [38], 'number': [41], 'electrons': [43], 'in': [44], 'cluster,': [46], 'belongs': [47], 'arachno-type': [50], 'group': [51], 'compounds': [53], '(see': [54], 'structure).': [55]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2141103276', 'counts_by_year': [{'year': 2023, 'cited_by_count': 1}, {'year': 2022, 'cited_by_count': 1}, {'year': 2019, 'cited_by_count': 2}, {'year': 2018, 'cited_by_count': 2}, {'year': 2017, 'cited_by_count': 3}, {'year': 2016, 'cited_by_count': 2}, {'year': 2013, 'cited_by_count': 2}], 'updated_date': '2025-01-09T08:54:39.618904', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
