Title: Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4‐Connected Metal–Organic Frameworks
Abstract: Angewandte Chemie International EditionVolume 48, Issue 52 p. 9905-9908 Communication Freeze Drying Significantly Increases Permanent Porosity and Hydrogen Uptake in 4,4-Connected Metal–Organic Frameworks† Liqing Ma Dr., Liqing Ma Dr. Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388 http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this authorAthena Jin, Athena Jin Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388 http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this authorZhigang Xie Dr., Zhigang Xie Dr. Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388 http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this authorWenbin Lin Prof., Wenbin Lin Prof. [email protected] Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388 http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this author Liqing Ma Dr., Liqing Ma Dr. Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388 http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this authorAthena Jin, Athena Jin Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388 http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this authorZhigang Xie Dr., Zhigang Xie Dr. Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388 http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this authorWenbin Lin Prof., Wenbin Lin Prof. [email protected] Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA), Fax: (+1) 919-962-2388 http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this author First published: 15 December 2009 https://doi.org/10.1002/anie.200904983Citations: 190 † We acknowledge financial support from NSF. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Freeze the flood: After replacing high boiling-point solvents inside the channels of a metal–organic framework (MOF), benzene is frozen and then removed under vacuum by sublimation. Bypassing the liquid phase eliminates the detrimental effects of surface tension that induce mesopore collapse in MOFs, thereby enhancing their permanent porosity and hydrogen-uptake capacity (see scheme). Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200904983_sm_miscellaneous_information.pdf1,007.3 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume48, Issue52December 21, 2009Pages 9905-9908 RelatedInformation
Publication Year: 2009
Publication Date: 2009-12-15
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 208
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