Thermal decomposition of Cu(I) phosphine complexes

Name: Work Video:
Duration: 3 min 30 s
Description: The thermal decomposition of Cu(I) phosphine complexes of the general types (CuXPPh3)4, [CuX(PPh3)2] and [CuX(PPh3)3] was investigated. The thermal decomposition of (CuXPPh3)4, where X denotes Cl−, Br−, I−, NO 3 − and PPh3=P(C6H5)3, occurs with formation of a phosphine oxide intermediate. For the remaining complexes this intermediate was not proved in the thermal decomposition.
František Březina; E. Benátsk↠
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