Title: Correlation between Surface-Crystallized ZnO and the Amount of Al2O3 in Borate-Based Glass-Ceramics
Abstract: Journal of the American Ceramic SocietyVolume 94, Issue 8 p. 2452-2457 Article Correlation between Surface-Crystallized ZnO and the Amount of Al2O3 in Borate-Based Glass-Ceramics Hirokazu Masai, Corresponding Author Hirokazu Masai Department of Applied Physics, Tohoku University 6-6-05, Aoba, Aoba-ku, Sendai, 980-8579 JapanAuthor to whom correspondence should be addressed. e-mail: [email protected] for more papers by this authorTakahiro Ueno, Takahiro Ueno Department of Applied Physics, Tohoku University 6-6-05, Aoba, Aoba-ku, Sendai, 980-8579 JapanSearch for more papers by this authorYoshihiro Takahashi, Yoshihiro Takahashi Department of Applied Physics, Tohoku University 6-6-05, Aoba, Aoba-ku, Sendai, 980-8579 JapanSearch for more papers by this authorTakumi Fujiwara, Takumi Fujiwara Department of Applied Physics, Tohoku University 6-6-05, Aoba, Aoba-ku, Sendai, 980-8579 JapanSearch for more papers by this author Hirokazu Masai, Corresponding Author Hirokazu Masai Department of Applied Physics, Tohoku University 6-6-05, Aoba, Aoba-ku, Sendai, 980-8579 JapanAuthor to whom correspondence should be addressed. e-mail: [email protected] for more papers by this authorTakahiro Ueno, Takahiro Ueno Department of Applied Physics, Tohoku University 6-6-05, Aoba, Aoba-ku, Sendai, 980-8579 JapanSearch for more papers by this authorYoshihiro Takahashi, Yoshihiro Takahashi Department of Applied Physics, Tohoku University 6-6-05, Aoba, Aoba-ku, Sendai, 980-8579 JapanSearch for more papers by this authorTakumi Fujiwara, Takumi Fujiwara Department of Applied Physics, Tohoku University 6-6-05, Aoba, Aoba-ku, Sendai, 980-8579 JapanSearch for more papers by this author First published: 03 June 2011 https://doi.org/10.1111/j.1551-2916.2011.04604.xCitations: 10 This work was partially supported by the Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sport and Culture, Japan, and the global century Center of Excellence (COE) Program in Tohoku University. Present address: Institute for Chemical Research, Kyoto University, Gokasyo, Uji, Kyoto 611-0011, Japan Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The correlation between the Al2O3 content and the crystallization behavior of the oxide semiconductor ZnO in 5CaO–25B2O3–45ZnO–xAl2O3–10K2O–15SiO2 (CaBZAKSx) glass-ceramics was investigated, with a particular focus on the c-oriented crystallization behavior of ZnO. C-oriented precipitation of ZnO crystallites in glass-ceramics is brought about by the in-plane crystal growth of ZnO along the a-axis. Addition of Al2O3 promotes the formation of ZnO4 rather than ZnO6 in the mother glass, and the ZnO4 unit affects the nucleation and selective crystallization of ZnO that also takes the four-coordination state of Zn. The present results suggest that crystallization of ZnO from multi-component glass is also dominated by the local coordination state of the mother glass. Citing Literature Volume94, Issue8August 2011Pages 2452-2457 RelatedInformation
Publication Year: 2011
Publication Date: 2011-06-03
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 10
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