Title: Highly Enantioselective Iron‐Catalyzed Sulfide Oxidation with Aqueous Hydrogen Peroxide under Simple Reaction Conditions
Abstract: Angewandte Chemie International EditionVolume 43, Issue 32 p. 4225-4228 Communication Highly Enantioselective Iron-Catalyzed Sulfide Oxidation with Aqueous Hydrogen Peroxide under Simple Reaction Conditions† Julien Legros Dr., Julien Legros Dr. Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Strasse 1, 52 056 Aachen, Germany, Fax: (+49) 241-809-2391Search for more papers by this authorCarsten Bolm Prof. Dr., Carsten Bolm Prof. Dr. [email protected] Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Strasse 1, 52 056 Aachen, Germany, Fax: (+49) 241-809-2391Search for more papers by this author Julien Legros Dr., Julien Legros Dr. Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Strasse 1, 52 056 Aachen, Germany, Fax: (+49) 241-809-2391Search for more papers by this authorCarsten Bolm Prof. Dr., Carsten Bolm Prof. Dr. [email protected] Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Strasse 1, 52 056 Aachen, Germany, Fax: (+49) 241-809-2391Search for more papers by this author First published: 09 August 2004 https://doi.org/10.1002/anie.200460236Citations: 217 † We are grateful to the Fonds der Chemischen Industrie and to the Deutsche Forschungsgemeinschaft (DFG) within the SFB 380 "Asymmetric Synthesis by Chemical and Biological Methods" for financial support. We thank the Alexander von Humboldt Foundation for a postdoctoral fellowship (J.L.). Degussa is acknowledged for gifts of (S)- and (R)-tert-leucine. J.-C. Frison and Dr. Y. Yuan are thanked for fruitful discussions. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract An attractive alternative to the currently existing methods for the metal-catalyzed oxidation of sulfides to sulfoxides is asymmetric iron-catalyzed oxidation with hydrogen peroxide as the terminal oxidant (see scheme). In the presence of a benzoic acid derivative, this simple process provides sulfoxides with up to 96 % ee in moderate to good yields (up to 78 %). Citing Literature Volume43, Issue32August 13, 2004Pages 4225-4228 RelatedInformation
Publication Year: 2004
Publication Date: 2004-08-09
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 238
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