Title: The Nature of Nitrogen‐Modified Titanium Dioxide Photocatalysts Active in Visible Light
Abstract: Angewandte Chemie International EditionVolume 47, Issue 51 p. 9975-9978 Communication The Nature of Nitrogen-Modified Titanium Dioxide Photocatalysts Active in Visible Light† Dariusz Mitoraj, Dariusz Mitoraj Department Chemie und Pharmazie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-852-7363Search for more papers by this authorHorst Kisch Prof. Dr., Horst Kisch Prof. Dr. [email protected] Department Chemie und Pharmazie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-852-7363Search for more papers by this author Dariusz Mitoraj, Dariusz Mitoraj Department Chemie und Pharmazie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-852-7363Search for more papers by this authorHorst Kisch Prof. Dr., Horst Kisch Prof. Dr. [email protected] Department Chemie und Pharmazie, Universität Erlangen-Nürnberg, Egerlandstr. 1, 91058 Erlangen (Germany), Fax: (+49) 9131-852-7363Search for more papers by this author First published: 04 December 2008 https://doi.org/10.1002/anie.200800304Citations: 335 † This work was supported by Deutsche Forschungsgemeinschaft (SFB 583). We thank H. Hildebrand for XPS measurements, S. Hoffmann for XRD measurements and R. Beránek for valuable discussions. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Can you see the light? Calcining a mixture of urea and TiO2 produces amino-tri-s-triazine derivatives covalently attached to TiO2 (see scheme). Therefore, the photocatalytic activity of this material in the visible range does not originate from surface defects or the presence of nitridic, amidic, or oxide species. This dye-sensitized titania efficiently photocatalyzes the oxidation of HCOOH to CO2 and H2O. Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200800304_sm_miscellaneous_information.pdf95.2 KB miscellaneous information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1D. A. Tryk, A. Fujishima, K. Honda, Electrochim. Acta 2000, 45, 2363. 2Throughout this paper we use the term “modifying” instead of “doping”, as in most cases it is unknown if the nonmetal really substitutes a lattice atom in the titania structure. 3For the recent reviews see: 3aX. Qiu, C. Burda, Chem. 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Hebenstreit, M. Schmid, P. Varga, Surf. Sci. 1998, 411, 137. Citing Literature Volume47, Issue51December 8, 2008Pages 9975-9978 ReferencesRelatedInformation
Publication Year: 2008
Publication Date: 2008-11-12
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 350
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