Title: CC Coupling and CH Bond Activation—Unexpected Pathways in the Reactions of [Yb(η<sup>5</sup>‐C<sub>13</sub>H<sub>9</sub>)<sub>2</sub>(thf)<sub>2</sub>] with Diazadienes
Abstract: Angewandte Chemie International EditionVolume 43, Issue 38 p. 5045-5048 Communication CC Coupling and CH Bond Activation—Unexpected Pathways in the Reactions of [Yb(η5-C13H9)2(thf)2] with Diazadienes† Alexander A. Trifonov Dr., Alexander A. Trifonov Dr. [email protected] G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this authorElena A. Fedorova Dr., Elena A. Fedorova Dr. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this authorGeorgy K. Fukin Dr., Georgy K. Fukin Dr. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this authorNikolai O. Druzhkov Dr., Nikolai O. Druzhkov Dr. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this authorMikhail N. Bochkarev Prof. Dr., Mikhail N. Bochkarev Prof. Dr. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this author Alexander A. Trifonov Dr., Alexander A. Trifonov Dr. [email protected] G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this authorElena A. Fedorova Dr., Elena A. Fedorova Dr. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this authorGeorgy K. Fukin Dr., Georgy K. Fukin Dr. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this authorNikolai O. Druzhkov Dr., Nikolai O. Druzhkov Dr. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this authorMikhail N. Bochkarev Prof. Dr., Mikhail N. Bochkarev Prof. Dr. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP-445, Russia, Fax: (+7) 8312-127-497Search for more papers by this author First published: 22 September 2004 https://doi.org/10.1002/anie.200461001Citations: 47 † This work was supported by the Russian Foundation of Basic Research (Grant No 02-03-32112), Grant of President of RF supporting scientific schools (No.58.2003.3). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract A couple of surprises: The reactions of [(C13H9)2Yb(thf)2] with diazadienes (2,6-iPr2C6H3)NCRCRN(2,6-iPr2C6H3) (R=H, Me) result in unexpected YbII complexes, which arise either from the coupling of the fluorene and the diazadiene ligands (when R=H, see picture) or from CH bond activation of the diazadiene ligand (when R=Me). References 1 1aH. tom Dieck, I. W. Renk, Chem. 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Publication Year: 2004
Publication Date: 2004-09-22
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 50
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