Title: Evaluation of a chiral aryl auxiliary design for sulfur: construction of auxiliary-modified reagents and stereoselection in sulfoxide formation
Abstract: Compounds possessing thiol, sulfide, and sulfoxide functionality attached to chiral auxiliary fragment 1 can be synthesized from halogenated aromatics 2 and 3. In the sulfoxides,auxiliary 1 can define the sulfinyl configuration in either relative sense depending on whether sulfinyl configuration is established under kinetic or thermodynamic control.
Publication Year: 1990
Publication Date: 1990-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 13
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