Title: Insights into the Mechanism of Methanol‐to‐Olefin Conversion at Zeolites with Systematically Selected Framework Structures
Abstract: Angewandte Chemie International EditionVolume 45, Issue 39 p. 6512-6515 Communication Insights into the Mechanism of Methanol-to-Olefin Conversion at Zeolites with Systematically Selected Framework Structures† Zhi-Min Cui, Zhi-Min Cui Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, P.R. China, Fax: (+86) 10-6255-7908Search for more papers by this authorQiang Liu, Qiang Liu Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, P.R. China, Fax: (+86) 10-6255-7908Search for more papers by this authorWei-Guo Song Prof., Wei-Guo Song Prof. [email protected] Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, P.R. China, Fax: (+86) 10-6255-7908Search for more papers by this author Li-Jun Wan Prof., Li-Jun Wan Prof. [email protected] Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, P.R. China, Fax: (+86) 10-6255-7908Search for more papers by this author Zhi-Min Cui, Zhi-Min Cui Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, P.R. China, Fax: (+86) 10-6255-7908Search for more papers by this authorQiang Liu, Qiang Liu Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, P.R. China, Fax: (+86) 10-6255-7908Search for more papers by this authorWei-Guo Song Prof., Wei-Guo Song Prof. [email protected] Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, P.R. China, Fax: (+86) 10-6255-7908Search for more papers by this author Li-Jun Wan Prof., Li-Jun Wan Prof. [email protected] Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, P.R. China, Fax: (+86) 10-6255-7908Search for more papers by this author First published: 29 September 2006 https://doi.org/10.1002/anie.200602488Citations: 105 † The authors thank the Natural Science Foundation of China (20121301), the Ministry of Science and Technology of China (2006CB806101), and the Chinese Academy of Sciences for financial support. Z.-M.C. and Q.L. thank Professor Chun-Li Bai for valuable advice. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Com-paring mechanisms: The so-called hydrocarbon pool mechanism does not operate with zeolite ZSM-22 in the methanol-to-olefin (MTO) conversion process as a result of the narrow channels (0.57 nm) in its framework structure. However, this provided a condition free of secondary reactions for detailed mechanistic studies, with H/D exchange patterns of toluene suggesting a paring mechanism. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z602488_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume45, Issue39October 6, 2006Pages 6512-6515 RelatedInformation
Publication Year: 2006
Publication Date: 2006-09-13
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 119
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