Title: A Stable Singlet Biradicaloid Siladicarbene: (L:)<sub>2</sub>Si
Abstract: Angewandte Chemie International EditionVolume 52, Issue 10 p. 2963-2967 Communication A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si† Dr. Kartik Chandra Mondal, Dr. Kartik Chandra Mondal Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorProf. Herbert W. Roesky, Corresponding Author Prof. Herbert W. Roesky [email protected] Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Herbert W. Roesky, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Gernot Frenking, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany) Dietmar Stalke, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorMartin C. Schwarzer, Martin C. Schwarzer Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany)Search for more papers by this authorProf. Gernot Frenking, Corresponding Author Prof. Gernot Frenking [email protected] Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany) Herbert W. Roesky, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Gernot Frenking, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany) Dietmar Stalke, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorBenedikt Niepötter, Benedikt Niepötter Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorHilke Wolf, Hilke Wolf Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorDr. Regine Herbst-Irmer, Dr. Regine Herbst-Irmer Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorProf. Dietmar Stalke, Corresponding Author Prof. Dietmar Stalke [email protected] Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Herbert W. Roesky, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Gernot Frenking, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany) Dietmar Stalke, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this author Dr. Kartik Chandra Mondal, Dr. Kartik Chandra Mondal Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorProf. Herbert W. Roesky, Corresponding Author Prof. Herbert W. Roesky [email protected] Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Herbert W. Roesky, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Gernot Frenking, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany) Dietmar Stalke, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorMartin C. Schwarzer, Martin C. Schwarzer Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany)Search for more papers by this authorProf. Gernot Frenking, Corresponding Author Prof. Gernot Frenking [email protected] Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany) Herbert W. Roesky, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Gernot Frenking, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany) Dietmar Stalke, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorBenedikt Niepötter, Benedikt Niepötter Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorHilke Wolf, Hilke Wolf Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorDr. Regine Herbst-Irmer, Dr. Regine Herbst-Irmer Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this authorProf. Dietmar Stalke, Corresponding Author Prof. Dietmar Stalke [email protected] Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Herbert W. Roesky, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany) Gernot Frenking, Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35032 Marburg (Germany) Dietmar Stalke, Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen (Germany)Search for more papers by this author First published: 10 January 2013 https://doi.org/10.1002/anie.201208307Citations: 228 † H.W.R. thanks the Deutsche Forschungsgemeinschaft (DFG RO 224/60-I) for support. We are grateful to Prof. Dr. Marina Bennati, Dr. Igor Tkach, Dr. Claudia Stückl for EPR and Felix Klinke for UV/Vis measurements. D.S. is grateful for funding from the DFG Priority Programme 1178, the DNRF-funded Center for Materials Crystallography (CMC) for support, and the Land Niedersachsen for providing a fellowship in the Catalysis for Sustainable Synthesis (CaSuS) Ph.D. program. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract A trapped silicon atom: The compound (L:)2Si with low-valent silicon was synthesized from its dichloride biradical precursor (L:)2SiCl2 by reduction with KC8. Theoretical analysis suggest that there are two donor–acceptor σ bonds L:→Si←:L. There is one σ lone-pair orbital at Si and one π orbital which features significant π-back-donation L:←Si→:L giving short SiC bonds. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201208307_sm_miscellaneous_information.pdf261 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume52, Issue10March 4, 2013Pages 2963-2967 RelatedInformation
Publication Year: 2013
Publication Date: 2013-01-10
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 253
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