Readily Available [2.2.2]-Bicyclooctadienes as New Chiral Ligands for Ir(I): Catalytic, Kinetic Resolution of Allyl Carbonates

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Duration: 3 min 30 s
Description: We report an Ir(I)-catalyzed kinetic resolution of secondary allylic carbonates allowing for their isolation in up to 98% ee. Importantly, the study documents the synthesis and use of a new class of chiral [2.2.2]-bicyclooctadiene ligands for iridium.
Christian Fischer; Christian Defieber; Takeyuki Suzuki; Erick M. Carreira
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