Ultrafast Deactivation Mechanism of the Excited Singlet in the Light‐Induced Spin Crossover of [Fe(2,2′‐bipyridine)<sub>3</sub>]<sup>2+</sup>

Name: Work Video:
Duration: 3 min 30 s
Carmen Sousa; Coen de Graaf; Andrii Rudavskyi; Ria Broer; Jörg Tatchen; Mihajlo Etinski; Christel M. Marian
{'id': 'https://openalex.org/W2122494045', 'doi': 'https://doi.org/10.1002/chem.201302992', 'title': 'Ultrafast Deactivation Mechanism of the Excited Singlet in the Light‐Induced Spin Crossover of [Fe(2,2′‐bipyridine)<sub>3</sub>]<sup>2+</sup>', 'display_name': 'Ultrafast Deactivation Mechanism of the Excited Singlet in the Light‐Induced Spin Crossover of [Fe(2,2′‐bipyridine)<sub>3</sub>]<sup>2+</sup>', 'publication_year': 2013, 'publication_date': '2013-11-07', 'ids': {'openalex': 'https://openalex.org/W2122494045', 'doi': 'https://doi.org/10.1002/chem.201302992', 'mag': '2122494045', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/24203780'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/chem.201302992', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S68911691', 'display_name': 'Chemistry - A European Journal', 'issn_l': '0947-6539', 'issn': ['0947-6539', '1521-3765'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5090175507', 'display_name': 'Carmen Sousa', 'orcid': 'https://orcid.org/0000-0002-1915-1111'}, 'institutions': [{'id': 'https://openalex.org/I71999127', 'display_name': 'Universitat de Barcelona', 'ror': 'https://ror.org/021018s57', 'country_code': 'ES', 'type': 'education', 'lineage': ['https://openalex.org/I71999127']}], 'countries': ['ES'], 'is_corresponding': False, 'raw_author_name': 'Carmen Sousa', 'raw_affiliation_strings': ['Departament de Química Física and Institut de Química Teòrica i Computacional, Universitat de Barcelona, C/Martí i Franquès 1,08028 Barcelona,Spain'], 'affiliations': [{'raw_affiliation_string': 'Departament de Química Física and Institut de Química Teòrica i Computacional, Universitat de Barcelona, C/Martí i Franquès 1,08028 Barcelona,Spain', 'institution_ids': ['https://openalex.org/I71999127']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5013260584', 'display_name': 'Coen de Graaf', 'orcid': 'https://orcid.org/0000-0001-8114-6658'}, 'institutions': [{'id': 'https://openalex.org/I11932220', 'display_name': 'Institució Catalana de Recerca i Estudis Avançats', 'ror': 'https://ror.org/0371hy230', 'country_code': 'ES', 'type': 'nonprofit', 'lineage': ['https://openalex.org/I11932220']}, {'id': 'https://openalex.org/I55952717', 'display_name': 'Universidad Rovira i Virgili', 'ror': 'https://ror.org/00g5sqv46', 'country_code': 'ES', 'type': 'education', 'lineage': ['https://openalex.org/I55952717']}, {'id': 'https://openalex.org/I169381384', 'display_name': 'University of Groningen', 'ror': 'https://ror.org/012p63287', 'country_code': 'NL', 'type': 'education', 'lineage': ['https://openalex.org/I169381384']}], 'countries': ['ES', 'NL'], 'is_corresponding': False, 'raw_author_name': 'Coen de\u2005Graaf', 'raw_affiliation_strings': ['Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Marcel-lí Domingo s/n, 43007 Tarragona (Spain), Fax: (+34)-977559563', 'Institució Catalana de Recerca i Estudis Avançats (ICREA), Passeig Lluís Companys 23, 08010 Barcelona (Spain)', 'Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen (The Netherlands)'], 'affiliations': [{'raw_affiliation_string': 'Institució Catalana de Recerca i Estudis Avançats (ICREA), Passeig Lluís Companys 23, 08010 Barcelona (Spain)', 'institution_ids': ['https://openalex.org/I11932220']}, {'raw_affiliation_string': 'Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Marcel-lí Domingo s/n, 43007 Tarragona (Spain), Fax: (+34)-977559563', 'institution_ids': ['https://openalex.org/I55952717']}, {'raw_affiliation_string': 'Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen (The Netherlands)', 'institution_ids': ['https://openalex.org/I169381384']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5069060607', 'display_name': 'Andrii Rudavskyi', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I169381384', 'display_name': 'University of Groningen', 'ror': 'https://ror.org/012p63287', 'country_code': 'NL', 'type': 'education', 'lineage': ['https://openalex.org/I169381384']}], 'countries': ['NL'], 'is_corresponding': False, 'raw_author_name': 'Andrii Rudavskyi', 'raw_affiliation_strings': ['Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.'], 'affiliations': [{'raw_affiliation_string': 'Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.', 'institution_ids': ['https://openalex.org/I169381384']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5042612904', 'display_name': 'Ria Broer', 'orcid': 'https://orcid.org/0000-0002-5437-9509'}, 'institutions': [{'id': 'https://openalex.org/I169381384', 'display_name': 'University of Groningen', 'ror': 'https://ror.org/012p63287', 'country_code': 'NL', 'type': 'education', 'lineage': ['https://openalex.org/I169381384']}], 'countries': ['NL'], 'is_corresponding': False, 'raw_author_name': 'Ria Broer', 'raw_affiliation_strings': ['Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.'], 'affiliations': [{'raw_affiliation_string': 'Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, the Netherlands.', 'institution_ids': ['https://openalex.org/I169381384']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5034344516', 'display_name': 'Jörg Tatchen', 'orcid': 'https://orcid.org/0000-0002-0264-311X'}, 'institutions': [{'id': 'https://openalex.org/I44260953', 'display_name': 'Heinrich Heine University Düsseldorf', 'ror': 'https://ror.org/024z2rq82', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I44260953']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Jörg Tatchen', 'raw_affiliation_strings': ['Institute of Theoretical and Computational Chemistry, Heinrich‐Heine University Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf (Germany)'], 'affiliations': [{'raw_affiliation_string': 'Institute of Theoretical and Computational Chemistry, Heinrich‐Heine University Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf (Germany)', 'institution_ids': ['https://openalex.org/I44260953']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5022068591', 'display_name': 'Mihajlo Etinski', 'orcid': 'https://orcid.org/0000-0003-0342-7045'}, 'institutions': [{'id': 'https://openalex.org/I4068193', 'display_name': 'University of Belgrade', 'ror': 'https://ror.org/02qsmb048', 'country_code': 'RS', 'type': 'education', 'lineage': ['https://openalex.org/I4068193']}], 'countries': ['RS'], 'is_corresponding': False, 'raw_author_name': 'Mihajlo Etinski', 'raw_affiliation_strings': ['Faculty of Physical Chemistry; University of Belgrade; Studentski trg 12-16, 11158 Belgrade Serbia'], 'affiliations': [{'raw_affiliation_string': 'Faculty of Physical Chemistry; University of Belgrade; Studentski trg 12-16, 11158 Belgrade Serbia', 'institution_ids': ['https://openalex.org/I4068193']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5037280717', 'display_name': 'Christel M. Marian', 'orcid': 'https://orcid.org/0000-0001-7148-0900'}, 'institutions': [{'id': 'https://openalex.org/I44260953', 'display_name': 'Heinrich Heine University Düsseldorf', 'ror': 'https://ror.org/024z2rq82', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I44260953']}], 'countries': ['DE'], 'is_corresponding': False, 'raw_author_name': 'Christel M. Marian', 'raw_affiliation_strings': ['Institute of Theoretical and Computational Chemistry, Heinrich‐Heine University Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf (Germany)'], 'affiliations': [{'raw_affiliation_string': 'Institute of Theoretical and Computational Chemistry, Heinrich‐Heine University Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf (Germany)', 'institution_ids': ['https://openalex.org/I44260953']}]}], 'institution_assertions': [], 'countries_distinct_count': 4, 'institutions_distinct_count': 6, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 4640, 'currency': 'USD', 'value_usd': 4640, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 5.403, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 149, 'citation_normalized_percentile': {'value': 0.999904, 'is_in_top_1_percent': True, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 98, 'max': 99}, 'biblio': {'volume': '19', 'issue': '51', 'first_page': '17541', 'last_page': '17551'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10612', 'display_name': 'Magnetism in coordination complexes', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/2504', 'display_name': 'Electronic, Optical and Magnetic Materials'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10612', 'display_name': 'Magnetism in coordination complexes', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/2504', 'display_name': 'Electronic, Optical and Magnetic Materials'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11747', 'display_name': 'Metal-Catalyzed Oxygenation Mechanisms', 'score': 0.9998, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11279', 'display_name': 'Lanthanide and Transition Metal Complexes', 'score': 0.9998, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/intersystem-crossing', 'display_name': 'Intersystem crossing', 'score': 0.9588396}, {'id': 'https://openalex.org/keywords/spin-states', 'display_name': 'Spin states', 'score': 0.59280217}, {'id': 'https://openalex.org/keywords/singlet-fission', 'display_name': 'Singlet fission', 'score': 0.5887564}, {'id': 'https://openalex.org/keywords/picosecond', 'display_name': 'Picosecond', 'score': 0.50012493}, {'id': 'https://openalex.org/keywords/spin-crossover', 'display_name': 'Spin Crossover', 'score': 0.49468395}, {'id': 'https://openalex.org/keywords/quantum-yield', 'display_name': 'Quantum yield', 'score': 0.4551667}], 'concepts': [{'id': 'https://openalex.org/C73978554', 'wikidata': 'https://www.wikidata.org/wiki/Q772919', 'display_name': 'Intersystem crossing', 'level': 4, 'score': 0.9588396}, {'id': 'https://openalex.org/C33062035', 'wikidata': 'https://www.wikidata.org/wiki/Q3296863', 'display_name': 'Singlet state', 'level': 3, 'score': 0.71672773}, {'id': 'https://openalex.org/C181500209', 'wikidata': 'https://www.wikidata.org/wiki/Q215328', 'display_name': 'Excited state', 'level': 2, 'score': 0.7040332}, {'id': 'https://openalex.org/C76766466', 'wikidata': 'https://www.wikidata.org/wiki/Q3036629', 'display_name': 'Triplet state', 'level': 3, 'score': 0.69074345}, {'id': 'https://openalex.org/C35325081', 'wikidata': 'https://www.wikidata.org/wiki/Q7577416', 'display_name': 'Spin states', 'level': 2, 'score': 0.59280217}, {'id': 'https://openalex.org/C161522054', 'wikidata': 'https://www.wikidata.org/wiki/Q17100192', 'display_name': 'Singlet fission', 'level': 4, 'score': 0.5887564}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.58187556}, {'id': 'https://openalex.org/C116039458', 'wikidata': 'https://www.wikidata.org/wiki/Q544431', 'display_name': 'Internal conversion', 'level': 3, 'score': 0.56588733}, {'id': 'https://openalex.org/C55005982', 'wikidata': 'https://www.wikidata.org/wiki/Q3902709', 'display_name': 'Picosecond', 'level': 3, 'score': 0.50012493}, {'id': 'https://openalex.org/C2777222292', 'wikidata': 'https://www.wikidata.org/wiki/Q2310676', 'display_name': 'Spin crossover', 'level': 2, 'score': 0.49468395}, {'id': 'https://openalex.org/C184779094', 'wikidata': 'https://www.wikidata.org/wiki/Q26383', 'display_name': 'Atomic physics', 'level': 1, 'score': 0.46948156}, {'id': 'https://openalex.org/C171001562', 'wikidata': 'https://www.wikidata.org/wiki/Q2856048', 'display_name': 'Quantum yield', 'level': 3, 'score': 0.4551667}, {'id': 'https://openalex.org/C42704618', 'wikidata': 'https://www.wikidata.org/wiki/Q910917', 'display_name': 'Spin (aerodynamics)', 'level': 2, 'score': 0.45491812}, {'id': 'https://openalex.org/C69523127', 'wikidata': 'https://www.wikidata.org/wiki/Q4480008', 'display_name': 'Ground state', 'level': 2, 'score': 0.45116192}, {'id': 'https://openalex.org/C75473681', 'wikidata': 'https://www.wikidata.org/wiki/Q188651', 'display_name': 'Photochemistry', 'level': 1, 'score': 0.38882425}, {'id': 'https://openalex.org/C41999313', 'wikidata': 'https://www.wikidata.org/wiki/Q489328', 'display_name': 'Molecular physics', 'level': 1, 'score': 0.3842795}, {'id': 'https://openalex.org/C159467904', 'wikidata': 'https://www.wikidata.org/wiki/Q2001702', 'display_name': 'Chemical physics', 'level': 1, 'score': 0.33325142}, {'id': 'https://openalex.org/C147120987', 'wikidata': 'https://www.wikidata.org/wiki/Q2225', 'display_name': 'Electron', 'level': 2, 'score': 0.25046352}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.20689031}, {'id': 'https://openalex.org/C91881484', 'wikidata': 'https://www.wikidata.org/wiki/Q191807', 'display_name': 'Fluorescence', 'level': 2, 'score': 0.17586225}, {'id': 'https://openalex.org/C8010536', 'wikidata': 'https://www.wikidata.org/wiki/Q160398', 'display_name': 'Crystallography', 'level': 1, 'score': 0.17583072}, {'id': 'https://openalex.org/C520434653', 'wikidata': 'https://www.wikidata.org/wiki/Q38867', 'display_name': 'Laser', 'level': 2, 'score': 0.0}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C120665830', 'wikidata': 'https://www.wikidata.org/wiki/Q14620', 'display_name': 'Optics', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C97355855', 'wikidata': 'https://www.wikidata.org/wiki/Q11473', 'display_name': 'Thermodynamics', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 2, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/chem.201302992', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S68911691', 'display_name': 'Chemistry - A European Journal', 'issn_l': '0947-6539', 'issn': ['0947-6539', '1521-3765'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/24203780', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [{'funder': 'https://openalex.org/F4320320300', 'funder_display_name': 'European Commission', 'award_id': None}, {'funder': 'https://openalex.org/F4320321505', 'funder_display_name': 'Generalitat de Catalunya', 'award_id': '2009SGR-1041'}, {'funder': 'https://openalex.org/F4320321505', 'funder_display_name': 'Generalitat de Catalunya', 'award_id': '2009SGR462'}, {'funder': 'https://openalex.org/F4320321800', 'funder_display_name': 'Nederlandse Organisatie voor Wetenschappelijk Onderzoek', 'award_id': None}], 'datasets': [], 'versions': [], 'referenced_works_count': 87, 'referenced_works': ['https://openalex.org/W1588465183', 'https://openalex.org/W1655886908', 'https://openalex.org/W1908170464', 'https://openalex.org/W1965027145', 'https://openalex.org/W1970155391', 'https://openalex.org/W1971621213', 'https://openalex.org/W1971706660', 'https://openalex.org/W1973454385', 'https://openalex.org/W1974481418', 'https://openalex.org/W1978852392', 'https://openalex.org/W1987268726', 'https://openalex.org/W1988091937', 'https://openalex.org/W1988996307', 'https://openalex.org/W1989021984', 'https://openalex.org/W1992854948', 'https://openalex.org/W1994136125', 'https://openalex.org/W1996368137', 'https://openalex.org/W1997641598', 'https://openalex.org/W1999909316', 'https://openalex.org/W2000728935', 'https://openalex.org/W2008423326', 'https://openalex.org/W2012114777', 'https://openalex.org/W2016029742', 'https://openalex.org/W2017802257', 'https://openalex.org/W2021634443', 'https://openalex.org/W2022261340', 'https://openalex.org/W2023071471', 'https://openalex.org/W2023390323', 'https://openalex.org/W2027862841', 'https://openalex.org/W2028022118', 'https://openalex.org/W2029065336', 'https://openalex.org/W2030380628', 'https://openalex.org/W2034596911', 'https://openalex.org/W2037621685', 'https://openalex.org/W2041132372', 'https://openalex.org/W2042555602', 'https://openalex.org/W2046471185', 'https://openalex.org/W2051178175', 'https://openalex.org/W2053995070', 'https://openalex.org/W2055983263', 'https://openalex.org/W2056817540', 'https://openalex.org/W2058398316', 'https://openalex.org/W2058764863', 'https://openalex.org/W2067872400', 'https://openalex.org/W2068228867', 'https://openalex.org/W2071095959', 'https://openalex.org/W2071202770', 'https://openalex.org/W2076346814', 'https://openalex.org/W2077028593', 'https://openalex.org/W2077420504', 'https://openalex.org/W2080447728', 'https://openalex.org/W2081679016', 'https://openalex.org/W2082020261', 'https://openalex.org/W2086391067', 'https://openalex.org/W2086439661', 'https://openalex.org/W2087526793', 'https://openalex.org/W2089740902', 'https://openalex.org/W2097213064', 'https://openalex.org/W2098847222', 'https://openalex.org/W2099289509', 'https://openalex.org/W2100113961', 'https://openalex.org/W2110576774', 'https://openalex.org/W2114715156', 'https://openalex.org/W2115109504', 'https://openalex.org/W2117868355', 'https://openalex.org/W2129125712', 'https://openalex.org/W2134002147', 'https://openalex.org/W2144045267', 'https://openalex.org/W2147340554', 'https://openalex.org/W2148536073', 'https://openalex.org/W2155600484', 'https://openalex.org/W2158494514', 'https://openalex.org/W2159470471', 'https://openalex.org/W2167636026', 'https://openalex.org/W2169135284', 'https://openalex.org/W2171520157', 'https://openalex.org/W2320069607', 'https://openalex.org/W2321530812', 'https://openalex.org/W2321783554', 'https://openalex.org/W2322690796', 'https://openalex.org/W2327027310', 'https://openalex.org/W2470683402', 'https://openalex.org/W2953008588', 'https://openalex.org/W4241049147', 'https://openalex.org/W4244568746', 'https://openalex.org/W4246655805', 'https://openalex.org/W4250451065'], 'related_works': ['https://openalex.org/W4294904633', 'https://openalex.org/W4247749456', 'https://openalex.org/W4243499601', 'https://openalex.org/W4234730215', 'https://openalex.org/W4226479261', 'https://openalex.org/W4200293812', 'https://openalex.org/W3188075723', 'https://openalex.org/W2169416631', 'https://openalex.org/W1986587543', 'https://openalex.org/W1974233216'], 'abstract_inverted_index': {'Abstract': [0], 'The': [1, 110, 146, 213], 'mechanism': [2], 'of': [3, 8, 61, 68, 72, 77, 106, 122, 142, 171], 'the': [4, 9, 34, 45, 58, 66, 75, 78, 86, 91, 103, 107, 119, 125, 132, 136, 186, 210, 217, 229, 235], 'light‐induced': [5], 'spin': [6, 95, 98], 'crossover': [7], '[Fe(bpy)': [10], '3': [11], ']': [12], '2+': [13], 'complex': [14, 133], '(bpy=2,2′‐bipyridine)': [15], 'has': [16, 55], 'been': [17], 'studied': [18], 'by': [19, 140, 169, 197], 'combining': [20], 'accurate': [21], 'electronic‐structure': [22], 'calculations': [23, 111], 'and': [24, 99, 129, 205], 'time‐dependent': [25], 'approaches': [26], 'to': [27, 44, 96, 154, 185, 200, 209, 216], 'calculate': [28], 'intersystem‐crossing': [29], 'rates.': [30], 'We': [31, 83], 'investigate': [32], 'how': [33], 'initially': [35], 'excited': [36, 149], 'metal‐to‐ligand': [37], 'charge': [38], 'transfer': [39], '(MLCT)': [40], 'singlet': [41, 150], 'state': [42, 139, 151, 157, 179, 204, 220], 'deactivates': [43], 'final': [46, 137, 187], 'metastable': [47], 'high‐spin': [48, 138, 211], 'state.': [49, 175, 212], 'Although': [50], 'ultrafast': [51], 'X‐ray': [52], 'free‐electron': [53], 'spectroscopy': [54], 'established': [56], 'that': [57, 131], 'total': [59, 115], 'timescale': [60], 'this': [62], 'process': [63], 'is': [64, 195, 221, 225], 'on': [65, 118], 'order': [67, 121], 'a': [69, 73, 114, 155, 172, 191, 201], 'few': [70], 'tenths': [71], 'picosecond,': [74], 'details': [76], 'mechanisms': [79], 'still': [80], 'remain': [81], 'unclear.': [82], 'determine': [84], 'all': [85], 'intermediate': [87], 'electronic': [88], 'states': [89], 'along': [90], 'pathway': [92], 'from': [93], 'low': [94], 'high': [97], 'give': [100], 'estimates': [101], 'for': [102, 234], 'deactivation': [104, 116, 144, 214], 'times': [105], 'different': [108, 143], 'stages.': [109], 'result': [112], 'in': [113, 181, 226], 'time': [117], 'same': [120], 'magnitude': [123], 'as': [124], 'experimentally': [126], 'determined': [127], 'rate': [128, 215], 'indicate': [130], 'can': [134], 'reach': [135], 'means': [141, 170], 'channels.': [145], 'optically': [147], 'populated': [148], 'rapidly': [152], 'decays': [153], 'triplet': [156, 173, 177, 203], 'with': [158, 228], 'an': [159], 'Fe': [160], 'd': [161], '6': [162], '(': [163], ')': [164], 'configuration': [165], 'either': [166], 'directly': [167, 184], 'or': [168], 'MLCT': [174], 'This': [176], 'ligand‐field': [178], 'could': [180], 'principle': [182], 'decay': [183], 'quintet': [188], 'state,': [189], 'but': [190], 'much': [192, 222], 'faster': [193], 'channel': [194], 'provided': [196], 'internal': [198], 'conversion': [199], 'lower‐lying': [202], 'subsequent': [206], 'intersystem': [207], 'crossing': [208], 'low‐spin': [218], 'ground': [219], 'smaller,': [223], 'which': [224], 'line': [227], 'large': [230], 'quantum': [231], 'yield': [232], 'reported': [233], 'process.': [236]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2122494045', 'counts_by_year': [{'year': 2024, 'cited_by_count': 7}, {'year': 2023, 'cited_by_count': 10}, {'year': 2022, 'cited_by_count': 14}, {'year': 2021, 'cited_by_count': 7}, {'year': 2020, 'cited_by_count': 12}, {'year': 2019, 'cited_by_count': 13}, {'year': 2018, 'cited_by_count': 15}, {'year': 2017, 'cited_by_count': 18}, {'year': 2016, 'cited_by_count': 14}, {'year': 2015, 'cited_by_count': 21}, {'year': 2014, 'cited_by_count': 15}, {'year': 2013, 'cited_by_count': 2}], 'updated_date': '2024-12-18T07:49:47.422198', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
