Title: Direct Observation of Hydrogen Molecules Adsorbed onto a Microporous Coordination Polymer
Abstract: Angewandte Chemie International EditionVolume 44, Issue 6 p. 920-923 Communication Direct Observation of Hydrogen Molecules Adsorbed onto a Microporous Coordination Polymer† Yoshiki Kubota Dr., Yoshiki Kubota Dr. [email protected] Department of Environmental Sciences, Faculty of Science, Osaka Women's University, Sakai, Osaka 590-0035, Japan, Fax: (+81) 72-222-4791Search for more papers by this authorMasaki Takata Dr., Masaki Takata Dr. Japan Synchrotron Radiation Research Institute/SPring-8, Sayo-gun, Hyogo 679-5198, Japan CREST, Japan Science and Technology AgencySearch for more papers by this authorRyotaro Matsuda, Ryotaro Matsuda Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, JapanSearch for more papers by this authorRyo Kitaura Dr., Ryo Kitaura Dr. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan Present address: Toyota Central Research and Development Laboratories, Inc. Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorSusumu Kitagawa Prof. Dr., Susumu Kitagawa Prof. Dr. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, JapanSearch for more papers by this authorKenichi Kato, Kenichi Kato Japan Synchrotron Radiation Research Institute/SPring-8, Sayo-gun, Hyogo 679-5198, Japan CREST, Japan Science and Technology AgencySearch for more papers by this authorMakoto Sakata Prof. Dr., Makoto Sakata Prof. Dr. Department of Applied Physics, Nagoya University, Nagoya 464-8603, JapanSearch for more papers by this authorTatsuo C. Kobayashi Prof. Dr., Tatsuo C. Kobayashi Prof. Dr. Department of Physics, Okayama University, Okayama 700-8530, JapanSearch for more papers by this author Yoshiki Kubota Dr., Yoshiki Kubota Dr. [email protected] Department of Environmental Sciences, Faculty of Science, Osaka Women's University, Sakai, Osaka 590-0035, Japan, Fax: (+81) 72-222-4791Search for more papers by this authorMasaki Takata Dr., Masaki Takata Dr. Japan Synchrotron Radiation Research Institute/SPring-8, Sayo-gun, Hyogo 679-5198, Japan CREST, Japan Science and Technology AgencySearch for more papers by this authorRyotaro Matsuda, Ryotaro Matsuda Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, JapanSearch for more papers by this authorRyo Kitaura Dr., Ryo Kitaura Dr. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, Japan Present address: Toyota Central Research and Development Laboratories, Inc. Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorSusumu Kitagawa Prof. Dr., Susumu Kitagawa Prof. Dr. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto 615-8510, JapanSearch for more papers by this authorKenichi Kato, Kenichi Kato Japan Synchrotron Radiation Research Institute/SPring-8, Sayo-gun, Hyogo 679-5198, Japan CREST, Japan Science and Technology AgencySearch for more papers by this authorMakoto Sakata Prof. Dr., Makoto Sakata Prof. Dr. Department of Applied Physics, Nagoya University, Nagoya 464-8603, JapanSearch for more papers by this authorTatsuo C. Kobayashi Prof. Dr., Tatsuo C. Kobayashi Prof. Dr. Department of Physics, Okayama University, Okayama 700-8530, JapanSearch for more papers by this author First published: 25 January 2005 https://doi.org/10.1002/anie.200461895Citations: 202 † This study was supported by CREST, JST, and JASRI/SPring-8 Nanotechnology Support Project of the Ministry of Education, Culture, Sports, Science, and Technology of Japan (Proposal No. 2004A0217-ND1b-np/BL-No. 02B2). This research was also supported by a grant-in-aid for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. The authors thank Dr. H. Tanaka for the computer program ENIGMA for the MEM analysis. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Trapped hydrogen molecules in the nanochannels of a copper coordination polymer were successfully observed by the synchrotron powder-diffraction method. The adsorbed molecules are located near one corner of the rectangular nanochannels, and the pockets of the pore walls are suited to the size of the hydrogen molecules (see picture). These results could provide guidelines for the design of hydrogen-storage materials. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z461895_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume44, Issue6January 28, 2005Pages 920-923 RelatedInformation
Publication Year: 2005
Publication Date: 2005-01-25
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 218
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