Title: Synthesis of Naphthalenediols by Aerobic Oxidation of Diisopropylnaphthalenes Catalyzed by <i>N</i>‐Hydroxyphthalimide (NHPI)/α,α′‐Azobisisobutyronitrile (AIBN)
Abstract: Abstract Naphthalenediols were successfully synthesized in a one‐pot reaction through the oxidation of diisopropylnaphthalenes with air catalyzed by N ‐hydroxyphthalimide (NHPI) combined with α,α′‐azobisisobutyronitrile (AIBN) followed by decomposition with sulfuric acid. Thus, the oxidation of 2,6‐diisopropylnaphthalene with air (20 atm) in the presence of AIBN (3 mol %) and NHPI (10 mol %) in CH 3 CN at 75 °C for 21 h followed by treatment with 0.3 M H 2 SO 4 gave 2,6‐naphthalenediol in 92% yield.
Publication Year: 2004
Publication Date: 2004-02-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 69
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