Title: Enantioselective Synthesis of Cyclopropanes That Contain Fluorinated Tertiary Stereogenic Carbon Centers: A Chiral α‐Fluoro Carbanion Strategy
Abstract: Angewandte Chemie International EditionVolume 51, Issue 28 p. 6966-6970 Communication Enantioselective Synthesis of Cyclopropanes That Contain Fluorinated Tertiary Stereogenic Carbon Centers: A Chiral α-Fluoro Carbanion Strategy† Correction(s) for this article Corrigendum: Enantioselective Synthesis of Cyclopropanes That Contain Fluorinated Tertiary Stereogenic Carbon Centers: A Chiral α-Fluoro Carbanion Strategy Xiao Shen, Wei Zhang, Lei Zhang, Tao Luo, Xiaolong Wan, Yucheng Gu, Jinbo Hu, Volume 52Issue 2Angewandte Chemie International Edition pages: 488-488 First Published online: December 28, 2012 Xiao Shen, Xiao Shen Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorDr. Wei Zhang, Dr. Wei Zhang Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorLei Zhang, Lei Zhang Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorTao Luo, Tao Luo Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorXiaolong Wan, Xiaolong Wan Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorDr. Yucheng Gu, Dr. Yucheng Gu Syngenta, Jealott's Hill International Research Centre Bracknell, Berkshire, RG42 6EY (UK)Search for more papers by this authorProf. Dr. Jinbo Hu, Corresponding Author Prof. Dr. Jinbo Hu [email protected] Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this author Xiao Shen, Xiao Shen Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorDr. Wei Zhang, Dr. Wei Zhang Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorLei Zhang, Lei Zhang Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorTao Luo, Tao Luo Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorXiaolong Wan, Xiaolong Wan Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this authorDr. Yucheng Gu, Dr. Yucheng Gu Syngenta, Jealott's Hill International Research Centre Bracknell, Berkshire, RG42 6EY (UK)Search for more papers by this authorProf. Dr. Jinbo Hu, Corresponding Author Prof. Dr. Jinbo Hu [email protected] Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai, 200032 (China)Search for more papers by this author First published: 11 June 2012 https://doi.org/10.1002/anie.201202451Citations: 76 † Support of our work by the National Natural Science Foundation of China (20825209 and 20832008), the National Basic Research Program of China (2012CB215500 and 2012CB821600), the Chinese Academy of Sciences, and the Syngenta PhD Studentship (to X.S.) is gratefully acknowledged. We thank Dr. John Clough of Syngenta at Jealott’s Hill International Research Centre for proofreading of the manuscript. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Chiral transfer: The fluorinated sulfoximine (see scheme; Ts=p-toluenesulfonyl) was synthesized and used as the first chiral fluoromethylenation reagent for the synthesis of cyclopropanes that contain fluorinated tertiary stereogenic carbon centers in good yields, good diastereoselectivity, and excellent enantioselectivity. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201202451_sm_miscellaneous_information.pdf2.4 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue28July 9, 2012Pages 6966-6970 RelatedInformation
Publication Year: 2012
Publication Date: 2012-06-11
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 90
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