Title: An Anomalous Endohedral Structure of Eu@C<sub>82</sub> Metallofullerenes
Abstract: Angewandte Chemie International EditionVolume 44, Issue 29 p. 4568-4571 Communication An Anomalous Endohedral Structure of Eu@C82 Metallofullerenes† Bao-Yun Sun Dr., Bao-Yun Sun Dr. Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan CREST, Japan Science Technology Corporation c/o Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan, Fax: (+81) 52-789-1169Search for more papers by this authorToshiki Sugai Dr., Toshiki Sugai Dr. Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan CREST, Japan Science Technology Corporation c/o Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan, Fax: (+81) 52-789-1169Search for more papers by this authorEiji Nishibori Dr., Eiji Nishibori Dr. Department of Applied Physics, Nagoya University, Nagoya 464-8603, JapanSearch for more papers by this authorKenichi Iwata, Kenichi Iwata Department of Applied Physics, Nagoya University, Nagoya 464-8603, JapanSearch for more papers by this authorMakoto Sakata Prof. Dr., Makoto Sakata Prof. Dr. Department of Applied Physics, Nagoya University, Nagoya 464-8603, JapanSearch for more papers by this authorMasaki Takata Prof. Dr., Masaki Takata Prof. Dr. Japan Synchrotron Radiation Research Institute, 1-1-1 Kato, Mikazuki-cho, Sayo-gun, Hyogo 679-5198, Japan CREST, Japan Science Technology CorporationSearch for more papers by this authorHisanori Shinohara Prof. Dr., Hisanori Shinohara Prof. Dr. [email protected] Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan CREST, Japan Science Technology Corporation c/o Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan, Fax: (+81) 52-789-1169Search for more papers by this author Bao-Yun Sun Dr., Bao-Yun Sun Dr. Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan CREST, Japan Science Technology Corporation c/o Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan, Fax: (+81) 52-789-1169Search for more papers by this authorToshiki Sugai Dr., Toshiki Sugai Dr. Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan CREST, Japan Science Technology Corporation c/o Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan, Fax: (+81) 52-789-1169Search for more papers by this authorEiji Nishibori Dr., Eiji Nishibori Dr. Department of Applied Physics, Nagoya University, Nagoya 464-8603, JapanSearch for more papers by this authorKenichi Iwata, Kenichi Iwata Department of Applied Physics, Nagoya University, Nagoya 464-8603, JapanSearch for more papers by this authorMakoto Sakata Prof. Dr., Makoto Sakata Prof. Dr. Department of Applied Physics, Nagoya University, Nagoya 464-8603, JapanSearch for more papers by this authorMasaki Takata Prof. Dr., Masaki Takata Prof. Dr. Japan Synchrotron Radiation Research Institute, 1-1-1 Kato, Mikazuki-cho, Sayo-gun, Hyogo 679-5198, Japan CREST, Japan Science Technology CorporationSearch for more papers by this authorHisanori Shinohara Prof. Dr., Hisanori Shinohara Prof. Dr. [email protected] Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan CREST, Japan Science Technology Corporation c/o Department of Chemistry, Nagoya University, Nagoya 464-8602, Japan, Fax: (+81) 52-789-1169Search for more papers by this author First published: 08 July 2005 https://doi.org/10.1002/anie.200500876Citations: 34 † H.S. thanks a CREST Program on Novel Carbon Nanotube Materials by the JST. The study was also supported by the Special Coordination Funds for Promoting Science and Technology of MEXT. B.-Y.S. thanks the Japan Society for the Promotion of Science (JSPS) for the postdoctoral fellowship for foreigner research. E.N. thanks the Iketani Foundation and the Toyota Riken Foundation. The synchrotron radiation experiments were performed at SPring-8 BL02B2 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract A question of symmetry: Unlike other mono-metallofullerenes, the cage structures of Eu@C82 (isomers I and III) have been shown to have Cs (no. 6) and C2v symmetry, respectively, by the maximum entropy method using synchrotron X-ray powder diffraction data. In both isomers (see structures) the Eu ion (turquoise) is located near the top of the carbon cage adjacent to a CC double bond. Citing Literature Supporting Information Supporting information for this article (the relative yields of the three isomers and experimental section) is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z500876_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume44, Issue29July 18, 2005Pages 4568-4571 RelatedInformation
Publication Year: 2005
Publication Date: 2005-07-08
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
Access and Citation
Cited By Count: 39
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot