Title: Alkane Metathesis Catalyzed by a Well‐Defined Silica‐Supported Mo Imido Alkylidene Complex: [(SiO)Mo(NAr)(CH<i>t</i>Bu)(CH<sub>2</sub><i>t</i>Bu)]
Abstract: A two-functions-in-one catalyst precursor allows an olefin metathesis catalyst to be turned into an alkane metathesis catalyst. A silica-supported alkyl alkylidene molybdenum complex containing an ancillary imido ligand is a highly active olefin metathesis catalyst and also acts as a catalyst precursor for alkane metathesis. This system involves a single metal with dual properties and shows that ancillary ligands are compatible with alkane metathesis reactions. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z602171_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Publication Year: 2006
Publication Date: 2006-09-11
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
Access and Citation
Cited By Count: 52
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot