Title: A Novel, Bipolar Polymeric Host for Highly Efficient Blue Electrophosphorescence: a Non‐Conjugated Poly(aryl ether) Containing Triphenylphosphine Oxide Units in the Electron‐Transporting Main Chain and Carbazole Units in Hole‐Transporting Side Chains
Abstract: Advanced MaterialsVolume 23, Issue 31 p. 3570-3574 Communication A Novel, Bipolar Polymeric Host for Highly Efficient Blue Electrophosphorescence: a Non-Conjugated Poly(aryl ether) Containing Triphenylphosphine Oxide Units in the Electron-Transporting Main Chain and Carbazole Units in Hole-Transporting Side Chains Shiyang Shao, Shiyang Shao State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China Graduate School of the Chinese Academy of Sciences, Beijing 100039, PR ChinaSearch for more papers by this authorJunqiao Ding, Corresponding Author Junqiao Ding [email protected] State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaState Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China.Search for more papers by this authorTengling Ye, Tengling Ye State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China Graduate School of the Chinese Academy of Sciences, Beijing 100039, PR ChinaSearch for more papers by this authorZhiyuan Xie, Zhiyuan Xie State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaSearch for more papers by this authorLixiang Wang, Corresponding Author Lixiang Wang [email protected] State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaState Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China.Search for more papers by this authorXiabin Jing, Xiabin Jing State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaSearch for more papers by this authorFosong Wang, Fosong Wang State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaSearch for more papers by this author Shiyang Shao, Shiyang Shao State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China Graduate School of the Chinese Academy of Sciences, Beijing 100039, PR ChinaSearch for more papers by this authorJunqiao Ding, Corresponding Author Junqiao Ding [email protected] State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaState Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China.Search for more papers by this authorTengling Ye, Tengling Ye State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China Graduate School of the Chinese Academy of Sciences, Beijing 100039, PR ChinaSearch for more papers by this authorZhiyuan Xie, Zhiyuan Xie State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaSearch for more papers by this authorLixiang Wang, Corresponding Author Lixiang Wang [email protected] State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaState Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR China.Search for more papers by this authorXiabin Jing, Xiabin Jing State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaSearch for more papers by this authorFosong Wang, Fosong Wang State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, PR ChinaSearch for more papers by this author First published: 04 July 2011 https://doi.org/10.1002/adma.201101074Citations: 107Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract A novel, bipolar polymeric host based on a poly(aryl ether) containing phosphine oxide units in the electron-transporting main chain and carbazole units in the hole-transporting side chains is designed and synthesized for blue electrophosphorescence. This polymeric host possesses a bipolar character and a high ET of 2.96 eV. The efficiency of blue-emitting PhPLEDs based on this polymeric host doped with FIrpic reaches 23.3 cd A−1 (EQE = 10.8%). Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description adma_201101074_sm_suppl.pdf270.9 KB suppl Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 Y. Kawamura, S. Yanagida, S. R. Forrest, J. Appl. Phys. 2002, 92, 87. 2 X. W. Chen, J. L. Liao, Y. M. Liang, M. O. Ahmed, H. E. Tseng, S. A. Chen, J. Am. Chem. Soc. 2003, 125, 636. 3 S. Tokito, M. Suzuki, F. Sato, M. Kamachi, K. Shirane, Org. Electron. 2003, 4, 105. 4 P. T. Furuta, L. Deng, S. Garon, M. E. Thompson, J. M. J. Fréchet, J. Am. Chem. Soc. 2004, 126, 15388. 5 X. Gong, W. L. Ma, J. C. Ostrowski, G. C. Bazan, D. Moses, A. J. Heeger, Adv. Mater. 2004, 16, 615. 6 Y. C. Chen, G. S. Huang, C. C. Hsiao, S. A. Chen, J. Am. Chem. Soc. 2006, 128, 8549. 7 J. X. Jiang, Y. H. Xu, W. Yang, R. Guan, Z. Q. Liu, H. Y. Zhen, Y. Cao, Adv. Mater. 2006, 18, 1769. 8 M. K. Mathai, V.-E. Choong, S. A. Choulis, B. Krummacher, F. So, Appl. Phys. Lett. 2006, 88, 243512. 9 C. H. Chien, S. F. Liao, C. H. Wu, C. F. Shu, S. Y. Chang, Y. Chi, P. T. Chou, C. H. Lai, Adv. Funct. Mater. 2008, 18, 1430. 10 A. Haldi, A. Kimyonok, B. Domercq, L. E. Hayden, S. C. Jones, S. R. Marder, M. Weck, B. Kippelen, Adv. Funct. Mater. 2008, 18, 3056. 11 S. P. Huang, T. H. Jen, Y. C. Chen, A. E. Hsiao, S. H. Yin, H. Y. Chen, S. A. Chen, J. Am. Chem. Soc. 2008, 130, 4699. 12 H. C. Yeh, C. H. Chien, P. I. Shih, M. C. Yuan, C. F. Shu, Macromolecules 2008, 41, 3801. 13 I. Takasu, Y. Mizuno, S. Uchikoga, S. Enomoto, T. Sawabe, A. Amano, A. Wada, J. Yoshida, T. Ono, Proc. SPIE 2009, 7415, 74150B. 14 Z. H. Ma, J. Q. Ding, B. H. Zhang, C. Y. Mei, Y. X. Cheng, Z. Y. Xie, L. X. Wang, X. B. Jing, F. S. Wang, Adv. Funct. Mater. 2010, 20, 138. 15 J. Liu, Q. Pei, Macromolecules 2010, 43, 9608. 16 K. Brunner, A. van Dijken, H. Borner, J. Bastiaansen, N. M. M. Kiggen, B. M. W. Langeveld, J. Am. Chem. Soc. 2004, 126, 6035. 17 H. H. Chou, C. H. Cheng, Adv. Mater. 2010, 22, 2468. 18 F. M. Hsu, C. H. Chien, P. I. Shih, C. F. Shu, Chem. Mater. 2009, 21, 1017. 19 E. Polikarpov, J. S. Swensen, N. Chopra, F. So, A. B. Padmaperuma, Appl. Phys. Lett. 2009, 94, 223304. 20 L. S. Sapochak, A. B. Padmaperuma, X. Y. Cai, J. L. Male, P. E. Burrows, J. Phys. Chem. C. 2008, 112, 7989. 21 S. O. Jeon, K. S. Yook, C. W. Joo, J. Y. Lee, Adv. Funct. Mater. 2009, 19, 3644. 22 S. O. Jeon, K. S. Yook, C. W. Joo, J. Y. Lee, Adv. Mater. 2010, 22, 1872. 23 S. O. Jeon, S. E. Jang, H. S. Son, J. Y. Lee, Adv. Mater. 2011, 23, 1436. 24 H. S. Son, C. W. Seo, J. Y. Lee, J. Mater. Chem. 2011, 21, 5638. 25 Z. L. Wu, Y. Xiong, J. H. Zou, L. Wang, J. C. Liu, Q. L. Chen, W. Yang, J. B. Peng, Y. Cao, Adv. Mater. 2008, 20, 2359. 26 S. H. Ye, Y. Q. Liu, J. M. Chen, K. Lu, W. P. Wu, C. Y. Du, Y. Liu, T. Wu, Z. G. Shuai, G. Yu, Adv. Mater. 2010, 22, 4167. 27 J. Q. Ding, B. H. Zhang, J. H. Lu, Z. Y. Xie, L. X. Wang, X. B. Jing, F. S. Wang, Adv. Mater. 2009, 21, 4983. 28 K. T. Nielsen, K. Bechgaard, F. C. Krebs, Macromolecules 2005, 38, 658. 29Detailed information about this polymer will be published elsewhere concerning the optimization of this series of bipolar polymeric hosts. 30 R. Steyrleuthner, S. Bange, D. Neher, J. Appl. Phys. 2009, 105, 064509. 31 Z. X. Wu, L. D. Wang, G. T. Lei, Y. Qiu, J. Appl. Phys. 2005, 97, 103105. 32 J. Ding, Q. Wang, L. Zhao, D. Ma, L. Wang, X. Jing, F. Wang, J. Mater. Chem. 2010, 20, 8126. 33 X. Y. Cai, A. B. Padmaperuma, L. S. Sapochak, P. A. Vecchi, P. E. Burrows, Appl. Phys. Lett. 2008, 92, 083308. Citing Literature Volume23, Issue31August 16, 2011Pages 3570-3574 ReferencesRelatedInformation
Publication Year: 2011
Publication Date: 2011-07-04
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
Access and Citation
Cited By Count: 109
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot