Title: Isolation and Characterization of Sc<sub>2</sub>C<sub>2</sub>@C<sub>68</sub>: A Metal‐Carbide Endofullerene with a Non‐IPR Carbon Cage
Abstract: Angewandte Chemie International EditionVolume 45, Issue 13 p. 2107-2111 Communication Isolation and Characterization of Sc2C2@C68: A Metal-Carbide Endofullerene with a Non-IPR Carbon Cage† Zhi-Qiang Shi Dr., Zhi-Qiang Shi Dr. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China, Fax: (+86) 10-6265-2120Search for more papers by this authorXin Wu, Xin Wu State Key Laboratory of Physical Chemistry of Solid Surface & Center for Theoretical Chemistry, Departmental of Chemistry, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047Search for more papers by this authorChun-Ru Wang Prof. Dr., Chun-Ru Wang Prof. Dr. [email protected] Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China, Fax: (+86) 10-6265-2120Search for more papers by this authorXin Lu Prof. Dr., Xin Lu Prof. Dr. [email protected] State Key Laboratory of Physical Chemistry of Solid Surface & Center for Theoretical Chemistry, Departmental of Chemistry, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047Search for more papers by this authorHisanori Shinohara Prof. Dr., Hisanori Shinohara Prof. Dr. [email protected] Department of Chemistry, Nagoya University, Nagoya, 464-8602, Japan, Fax: (+81) 52-789-2962Search for more papers by this author Zhi-Qiang Shi Dr., Zhi-Qiang Shi Dr. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China, Fax: (+86) 10-6265-2120Search for more papers by this authorXin Wu, Xin Wu State Key Laboratory of Physical Chemistry of Solid Surface & Center for Theoretical Chemistry, Departmental of Chemistry, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047Search for more papers by this authorChun-Ru Wang Prof. Dr., Chun-Ru Wang Prof. Dr. [email protected] Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China, Fax: (+86) 10-6265-2120Search for more papers by this authorXin Lu Prof. Dr., Xin Lu Prof. Dr. [email protected] State Key Laboratory of Physical Chemistry of Solid Surface & Center for Theoretical Chemistry, Departmental of Chemistry, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047Search for more papers by this authorHisanori Shinohara Prof. Dr., Hisanori Shinohara Prof. Dr. [email protected] Department of Chemistry, Nagoya University, Nagoya, 464-8602, Japan, Fax: (+81) 52-789-2962Search for more papers by this author First published: 13 March 2006 https://doi.org/10.1002/anie.200503705Citations: 162 † C.-R.W. thanks NSFC (No. 50225206, 90206045, 20121301), National Key Project on Basic Research (Grant 2006CB30040, 2003CB716900), and National Center for Nanoscience and Technology of China. X.L. thanks NSFC (No. 20021002, 20425312, 20203013, 20423002, 90206038). H.S. thanks the JSPS for Future Program on New Carbon Nano-Materials for Financial support. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Breaking the rule: The metal-carbide endofullerene Sc2C2@C68 was isolated and characterized (see picture). It has a valence state (Sc3+)2(C2)2−@C684−, and its carbon cage does not comply with the isolated-pentagon rule (IPR). This result, in combination with previous work on Sc3N@C68, shows that different non-IPR C68 cages can be synthesized by using different endohedral clusters as templates. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z503705_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume45, Issue13March 20, 2006Pages 2107-2111 RelatedInformation
Publication Year: 2006
Publication Date: 2006-03-13
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 176
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