Title: The Li(+)-Initiated Twofold Dehydrogenation and C-C Bond Formation of Hexaphenylbenzene to the Dilithium Salt of the 9,10-Diphenyltetrabenz
Abstract:Partly solvent-separated and partly solvent-shared, the contact ion triple of the 9,10-diphenyltetrabenz[a,c,h,j]anthracene dianion is formed by the ultrasonically activated reaction of hexaphenylbenz...Partly solvent-separated and partly solvent-shared, the contact ion triple of the 9,10-diphenyltetrabenz[a,c,h,j]anthracene dianion is formed by the ultrasonically activated reaction of hexaphenylbenzene with lithium metal powder in 1,2-dimethoxyethane (dme) [Eq. (1)]. The proposed microscopic pathway for this reaction-twofold dehydrogenation and C-C bond formation-is supported by quantum-chemical calculations.Read More
Publication Year: 1999
Publication Date: 1999-08-01
Language: en
Type: article
Indexed In: ['pubmed']
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Cited By Count: 23
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