Title: Regio‐ and Stereocontrolled Total Synthesis of Benanomicin B
Abstract: Angewandte Chemie International EditionVolume 44, Issue 25 p. 3871-3874 Communication Regio- and Stereocontrolled Total Synthesis of Benanomicin B† Ken Ohmori Dr., Ken Ohmori Dr. Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorMinoru Tamiya, Minoru Tamiya Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorMitsuru Kitamura Dr., Mitsuru Kitamura Dr. Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorHirohisa Kato Dr., Hirohisa Kato Dr. Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorMami Oorui, Mami Oorui Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorKeisuke Suzuki Prof. Dr., Keisuke Suzuki Prof. Dr. [email protected] Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this author Ken Ohmori Dr., Ken Ohmori Dr. Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorMinoru Tamiya, Minoru Tamiya Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorMitsuru Kitamura Dr., Mitsuru Kitamura Dr. Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorHirohisa Kato Dr., Hirohisa Kato Dr. Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorMami Oorui, Mami Oorui Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this authorKeisuke Suzuki Prof. Dr., Keisuke Suzuki Prof. Dr. [email protected] Department of Chemistry, Tokyo Institute of Technology, SORST-JST Agency, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Fax: (+81) 3-5734-2788Search for more papers by this author First published: 10 June 2005 https://doi.org/10.1002/anie.200501210Citations: 63 † We thank Meiji Seika Kaisha Ltd. for providing an authentic sample of benanomicins A and B. This work was partially supported by the 21st Century COE program (Tokyo Institute of Technology). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Fully controlled total synthesis of benanomicin B was achieved by exploiting two key steps: a stereocontrolled ring-opening of a lactone (see scheme, step A), and a semipinacol cyclization of an acetal-aldehyde derivative discriminating the two hydroxy groups of the pseudo-C2-symmetric 1,2-diol moiety (step B). Citing Literature Volume44, Issue25June 20, 2005Pages 3871-3874 RelatedInformation
Publication Year: 2005
Publication Date: 2005-06-10
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 68
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