Title: A dimethyldioxirane-mediated route to enantiomerically pure tricarbonylchromium(0) complexes of ortho-substituted styrenes
Abstract: Dimethyldioxirane oxidation of tricarbonylchromium(0) complexes of a range of ortho-substituted (S)-α-methylbenzyldimethylamines 3a–f proceeds smoothly to give enantiomerically pure tricarbonylchromium(0) complexes of ortho-substituted styrenes 4a–fvia chemoselective oxidation of the tertiary amines to their N-oxides and subsequent Cope reactions.
Publication Year: 1994
Publication Date: 1994-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 15
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