Title: A Discrete P⋅⋅⋅II⋅⋅⋅P Assembly: The Large Influence of Weak Interactions on the <sup>31</sup>P NMR Spectra of Phosphane–Diiodine Complexes
Abstract: Angewandte Chemie International EditionVolume 45, Issue 8 p. 1270-1272 Communication A Discrete P⋅⋅⋅II⋅⋅⋅P Assembly: The Large Influence of Weak Interactions on the 31P NMR Spectra of Phosphane–Diiodine Complexes† Rosario Núñez Dr., Rosario Núñez Dr. Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., 08193 Bellaterra, Spain, Fax: (+34) 935805729Search for more papers by this authorPau Farràs, Pau Farràs Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., 08193 Bellaterra, Spain, Fax: (+34) 935805729Search for more papers by this authorFrancesc Teixidor Prof., Francesc Teixidor Prof. Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., 08193 Bellaterra, Spain, Fax: (+34) 935805729Search for more papers by this authorClara Viñas Dr., Clara Viñas Dr. [email protected] Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., 08193 Bellaterra, Spain, Fax: (+34) 935805729Search for more papers by this authorReijo Sillanpää Prof., Reijo Sillanpää Prof. Department of Chemistry, University of Jyväskylä, FIN-40351 Jyväskylä, FinlandSearch for more papers by this authorRaikko Kivekäs Dr., Raikko Kivekäs Dr. Department of Chemistry, PO Box 55, FIN-00014 University of Helsinki, FinlandSearch for more papers by this author Rosario Núñez Dr., Rosario Núñez Dr. Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., 08193 Bellaterra, Spain, Fax: (+34) 935805729Search for more papers by this authorPau Farràs, Pau Farràs Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., 08193 Bellaterra, Spain, Fax: (+34) 935805729Search for more papers by this authorFrancesc Teixidor Prof., Francesc Teixidor Prof. Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., 08193 Bellaterra, Spain, Fax: (+34) 935805729Search for more papers by this authorClara Viñas Dr., Clara Viñas Dr. [email protected] Institut de Ciència de Materials de Barcelona (CSIC), Campus de la U.A.B., 08193 Bellaterra, Spain, Fax: (+34) 935805729Search for more papers by this authorReijo Sillanpää Prof., Reijo Sillanpää Prof. Department of Chemistry, University of Jyväskylä, FIN-40351 Jyväskylä, FinlandSearch for more papers by this authorRaikko Kivekäs Dr., Raikko Kivekäs Dr. Department of Chemistry, PO Box 55, FIN-00014 University of Helsinki, FinlandSearch for more papers by this author First published: 06 February 2006 https://doi.org/10.1002/anie.200503007Citations: 96 † This work was supported, in part, by MAT2004-01108 and the Generalitat de Catalunya, 2001/SGR/00337. P. Farràs is enrolled in the UAB PhD program. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Seeing I to I: The reaction of a weakly coordinating carboranyl phosphane ligand with I2 leads to the formation of an adduct containing the bridging P⋅⋅⋅II⋅⋅⋅P assembly in the solid state (see picture; I purple, P orange, C gray, B pink, H white). DFT calculations combined with a variety of experimental techniques suggest that this structural motif also exists in solution. References 1"Product Subclass 40: Carboranes and Metallacarboranes": F. Teixidor, C. 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Volume45, Issue8February 13, 2006Pages 1270-1272 ReferencesRelatedInformation