Title: Tsuji–Trost Allylic Alkylation with Ketone Enolates
Abstract: Angewandte Chemie International EditionVolume 45, Issue 42 p. 6952-6955 Highlight Tsuji–Trost Allylic Alkylation with Ketone Enolates Manfred Braun Prof. Dr., Manfred Braun Prof. Dr. [email protected] Institut für Organische Chemie und Makromolekulare Chemie I, Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-81-15079Search for more papers by this authorThorsten Meier Dr., Thorsten Meier Dr. Institut für Organische Chemie und Makromolekulare Chemie I, Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-81-15079Search for more papers by this author Manfred Braun Prof. Dr., Manfred Braun Prof. Dr. [email protected] Institut für Organische Chemie und Makromolekulare Chemie I, Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-81-15079Search for more papers by this authorThorsten Meier Dr., Thorsten Meier Dr. Institut für Organische Chemie und Makromolekulare Chemie I, Universität Düsseldorf, Universitätsstrasse 1, 40225 Düsseldorf, Germany, Fax: (+49) 211-81-15079Search for more papers by this author First published: 23 October 2006 https://doi.org/10.1002/anie.200602169Citations: 149Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract The traditional restriction of the palladium-catalyzed allylation to stabilized carbanions has been overcome. Recent studies reveal that preformed "hard" enolates can serve as nucleophiles, and routes to novel stereoselective variants of the Tsuji–Trost method have thus been opened. References 1 1aB. M. Trost, Pure Appl. Chem. 1981, 53, 2357; 10.1351/pac198153122357 CASWeb of Science®Google Scholar 1bJ. Tsuji, Pure Appl. Chem. 1982, 54, 197; 10.1351/pac198254010197 CASWeb of Science®Google Scholar 1cB. M. Trost, T. R. Verhoeven in Comprehensive Organometallic Chemistry, Vol. 8 (Eds.: ), Pergamon, Oxford, 1982, p. 799; 10.1016/B978-008046518-0.00121-5 Google Scholar 1dJ. A. Davies in Comprehensive Organometallic Chemistry II, Vol. 9 (Eds.: ), Pergamon, Oxford, 1995, p. 323. Google Scholar 2Reviews: Google Scholar 2aO. Reiser, Angew. 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Publication Year: 2006
Publication Date: 2006-10-23
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 156
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