Title: No Contribution of an Inductive Effect to Secondary Deuterium Isotope Effects on Acidity
Abstract: Angewandte Chemie International EditionVolume 50, Issue 33 p. 7674-7676 Communication No Contribution of an Inductive Effect to Secondary Deuterium Isotope Effects on Acidity† Prof. Charles L. Perrin, Corresponding Author Prof. Charles L. Perrin [email protected] Department of Chemistry & Biochemistry, University of California—San Diego, La Jolla, CA 92093-0358 (USA)Department of Chemistry & Biochemistry, University of California—San Diego, La Jolla, CA 92093-0358 (USA)Search for more papers by this authorAgnes Flach, Agnes Flach Department of Chemistry & Biochemistry, University of California—San Diego, La Jolla, CA 92093-0358 (USA)Search for more papers by this author Prof. Charles L. Perrin, Corresponding Author Prof. Charles L. Perrin [email protected] Department of Chemistry & Biochemistry, University of California—San Diego, La Jolla, CA 92093-0358 (USA)Department of Chemistry & Biochemistry, University of California—San Diego, La Jolla, CA 92093-0358 (USA)Search for more papers by this authorAgnes Flach, Agnes Flach Department of Chemistry & Biochemistry, University of California—San Diego, La Jolla, CA 92093-0358 (USA)Search for more papers by this author First published: 24 June 2011 https://doi.org/10.1002/anie.201102125Citations: 21 † This research was supported by NSF Grant CHE07-42801. Purchase of the NMR spectrometer was made possible by NSF Grant CHE-0741968. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Effect and cause: Secondary deuterium isotope effects on the acidity of the deuterated compounds 1–4 were measured by using an NMR titration method applicable to a mixture and capable of very high accuracy. Variable-temperature experiments show that these isotope effects are due only to changes in vibrational frequencies. These findings refute an inductive origin for these isotope effects. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201102125_sm_miscellaneous_information.pdf134.8 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume50, Issue33August 8, 2011Pages 7674-7676 RelatedInformation
Publication Year: 2011
Publication Date: 2011-06-24
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 25
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