Title: The Pagodane Route to Dodecahedranes: Dodecahedradienes—Unusually “Pyramidalized”, Isolable Olefins
Abstract: The highly strained, extremely energy-rich dodecahedradienes 2 and 3 with plane-parallel CC double bonds are accessible by thermolysis of the bislactone 1 and via the SN2 variant of the pagodane-dodecahedrane route, respectively. Owing to strong “pyramidalization” these dienes are extremely sensitive to oxygen, but thermally very stable. Both can be hydrogenated to dedecahedrane.
Publication Year: 1990
Publication Date: 1990-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 36
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