Title: Oxidative Dimerization of Aromatic Amines using <i>t</i>BuOI: Entry to Unsymmetric Aromatic Azo Compounds
Abstract: Angewandte Chemie International EditionVolume 51, Issue 31 p. 7804-7808 Communication Oxidative Dimerization of Aromatic Amines using tBuOI: Entry to Unsymmetric Aromatic Azo Compounds† Dr. Youhei Takeda, Dr. Youhei Takeda Frontier Research Base for Global Young Researchers, Graduate School of Engineering, Osaka University, Osaka 565-0871 (Japan) Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan) http://www.chem.eng.osaka-u.ac.jp/∼minakata-lab/Search for more papers by this authorSota Okumura, Sota Okumura Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan) http://www.chem.eng.osaka-u.ac.jp/∼minakata-lab/Search for more papers by this authorProf. Dr. Satoshi Minakata, Corresponding Author Prof. Dr. Satoshi Minakata [email protected] Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan) http://www.chem.eng.osaka-u.ac.jp/∼minakata-lab/Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan) http://www.chem.eng.osaka-u.ac.jp/∼minakata-lab/Search for more papers by this author Dr. Youhei Takeda, Dr. Youhei Takeda Frontier Research Base for Global Young Researchers, Graduate School of Engineering, Osaka University, Osaka 565-0871 (Japan) Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan) http://www.chem.eng.osaka-u.ac.jp/∼minakata-lab/Search for more papers by this authorSota Okumura, Sota Okumura Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan) http://www.chem.eng.osaka-u.ac.jp/∼minakata-lab/Search for more papers by this authorProf. Dr. Satoshi Minakata, Corresponding Author Prof. Dr. Satoshi Minakata [email protected] Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan) http://www.chem.eng.osaka-u.ac.jp/∼minakata-lab/Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan) http://www.chem.eng.osaka-u.ac.jp/∼minakata-lab/Search for more papers by this author First published: 27 June 2012 https://doi.org/10.1002/anie.201202786Citations: 88 † This research was supported by a Grant-in-Aid for Scientific Research on Innovative Areas, "Molecular Activation Directed toward Straightforward Synthesis", from the MEXT (Japan). Y.T. acknowledges support from the Frontier Research Base for Global Young Researchers, Osaka University, from the Program of MEXT. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract It's all the hype: An oxidative dimerization reaction of aromatic amines utilizing tert-butyl hypoiodite (tBuOI) under mild reaction conditions leads to aromatic azo compounds (see scheme). The method allows access to unsymmetric aromatic azo compounds, which are difficult to prepare by conventional synthetic methods, in a selective manner. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201202786_sm_miscellaneous_information.pdf5.1 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue31July 27, 2012Pages 7804-7808 RelatedInformation
Publication Year: 2012
Publication Date: 2012-06-27
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 113
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