Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W2097097278', 'doi': 'https://doi.org/10.1002/poc.1418', 'title': 'Kinetics and mechanism of the anilinolysis of <i>S</i>‐aryl <i>N</i>‐arylthiocarbamates in acetonitrile', 'display_name': 'Kinetics and mechanism of the anilinolysis of <i>S</i>‐aryl <i>N</i>‐arylthiocarbamates in acetonitrile', 'publication_year': 2008, 'publication_date': '2008-07-10', 'ids': {'openalex': 'https://openalex.org/W2097097278', 'doi': 'https://doi.org/10.1002/poc.1418', 'mag': '2097097278'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/poc.1418', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S157344032', 'display_name': 'Journal of Physical Organic Chemistry', 'issn_l': '0894-3230', 'issn': ['0894-3230', '1099-1395'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5103554256', 'display_name': 'Dae Dong Sung', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I51226738', 'display_name': 'Dong-A University', 'ror': 'https://ror.org/03qvtpc38', 'country_code': 'KR', 'type': 'education', 'lineage': ['https://openalex.org/I51226738']}], 'countries': ['KR'], 'is_corresponding': False, 'raw_author_name': 'Dae Dong Sung', 'raw_affiliation_strings': ['Department of Chemistry, Dong‐A University, Busan 604‐714, Korea'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Dong‐A University, Busan 604‐714, Korea', 'institution_ids': ['https://openalex.org/I51226738']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5056922541', 'display_name': 'Hee Man Jang', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I51226738', 'display_name': 'Dong-A University', 'ror': 'https://ror.org/03qvtpc38', 'country_code': 'KR', 'type': 'education', 'lineage': ['https://openalex.org/I51226738']}], 'countries': ['KR'], 'is_corresponding': False, 'raw_author_name': 'Hee Man Jang', 'raw_affiliation_strings': ['Department of Chemistry, Dong‐A University, Busan 604‐714, Korea'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Dong‐A University, Busan 604‐714, Korea', 'institution_ids': ['https://openalex.org/I51226738']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5075951812', 'display_name': 'Dae Il Jung', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I51226738', 'display_name': 'Dong-A University', 'ror': 'https://ror.org/03qvtpc38', 'country_code': 'KR', 'type': 'education', 'lineage': ['https://openalex.org/I51226738']}], 'countries': ['KR'], 'is_corresponding': False, 'raw_author_name': 'Dae Il Jung', 'raw_affiliation_strings': ['Department of Chemistry, Dong‐A University, Busan 604‐714, Korea'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Dong‐A University, Busan 604‐714, Korea', 'institution_ids': ['https://openalex.org/I51226738']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5022650579', 'display_name': 'Ikchoon Lee', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I191879574', 'display_name': 'Inha University', 'ror': 'https://ror.org/01easw929', 'country_code': 'KR', 'type': 'education', 'lineage': ['https://openalex.org/I191879574']}], 'countries': ['KR'], 'is_corresponding': False, 'raw_author_name': 'Ikchoon Lee', 'raw_affiliation_strings': ['Department of Chemistry, Inha University Inchon 402 - 751, Korea'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Inha University Inchon 402 - 751, Korea', 'institution_ids': ['https://openalex.org/I191879574']}]}], 'countries_distinct_count': 1, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 3660, 'currency': 'USD', 'value_usd': 3660, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 1.04, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 14, 'citation_normalized_percentile': {'value': 0.559093, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 86, 'max': 87}, 'biblio': {'volume': '21', 'issue': '11', 'first_page': '1014', 'last_page': '1019'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T12191', 'display_name': 'Nucleophilic Reactivity in Organic Chemistry', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T12191', 'display_name': 'Nucleophilic Reactivity in Organic Chemistry', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T14068', 'display_name': 'Superelectrophilic Chemistry', 'score': 0.9989, 'subfield': {'id': 'https://openalex.org/subfields/1607', 'display_name': 'Spectroscopy'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T13253', 'display_name': 'Chemical Reactions Involving Quantum Tunneling', 'score': 0.9961, 'subfield': {'id': 'https://openalex.org/subfields/1606', 'display_name': 'Physical and Theoretical Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/leaving-group', 'display_name': 'Leaving group', 'score': 0.6333467}, {'id': 'https://openalex.org/keywords/aminolysis', 'display_name': 'Aminolysis', 'score': 0.510988}, {'id': 'https://openalex.org/keywords/concerted-reaction', 'display_name': 'Concerted reaction', 'score': 0.48368105}], 'concepts': [{'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.9725696}, {'id': 'https://openalex.org/C2777998946', 'wikidata': 'https://www.wikidata.org/wiki/Q4746464', 'display_name': 'Aminolysis', 'level': 3, 'score': 0.972224}, {'id': 'https://openalex.org/C192604958', 'wikidata': 'https://www.wikidata.org/wiki/Q7706517', 'display_name': 'Tetrahedral carbonyl addition compound', 'level': 4, 'score': 0.83817196}, {'id': 'https://openalex.org/C178907741', 'wikidata': 'https://www.wikidata.org/wiki/Q745930', 'display_name': 'Nucleophile', 'level': 3, 'score': 0.8185481}, {'id': 'https://openalex.org/C2777463227', 'wikidata': 'https://www.wikidata.org/wiki/Q408047', 'display_name': 'Acetonitrile', 'level': 2, 'score': 0.72696483}, {'id': 'https://openalex.org/C160964918', 'wikidata': 'https://www.wikidata.org/wiki/Q320141', 'display_name': 'Leaving group', 'level': 3, 'score': 0.6333467}, {'id': 'https://openalex.org/C2781076698', 'wikidata': 'https://www.wikidata.org/wiki/Q718074', 'display_name': 'Aryl', 'level': 3, 'score': 0.5949367}, {'id': 'https://openalex.org/C131779359', 'wikidata': 'https://www.wikidata.org/wiki/Q471875', 'display_name': 'Amine gas treating', 'level': 2, 'score': 0.5868468}, {'id': 'https://openalex.org/C155647269', 'wikidata': 'https://www.wikidata.org/wiki/Q243455', 'display_name': 'Medicinal chemistry', 'level': 1, 'score': 0.55707383}, {'id': 'https://openalex.org/C29135686', 'wikidata': 'https://www.wikidata.org/wiki/Q2733609', 'display_name': 'Concerted reaction', 'level': 3, 'score': 0.48368105}, {'id': 'https://openalex.org/C93391505', 'wikidata': 'https://www.wikidata.org/wiki/Q658700', 'display_name': 'Reaction rate constant', 'level': 3, 'score': 0.4216223}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.38288164}, {'id': 'https://openalex.org/C148898269', 'wikidata': 'https://www.wikidata.org/wiki/Q1108792', 'display_name': 'Kinetics', 'level': 2, 'score': 0.38281426}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.17726612}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.15060082}, {'id': 'https://openalex.org/C2780263894', 'wikidata': 'https://www.wikidata.org/wiki/Q335268', 'display_name': 'Alkyl', 'level': 2, 'score': 0.0}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1002/poc.1418', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S157344032', 'display_name': 'Journal of Physical Organic Chemistry', 'issn_l': '0894-3230', 'issn': ['0894-3230', '1099-1395'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'score': 0.5, 'display_name': 'Clean water and sanitation', 'id': 'https://metadata.un.org/sdg/6'}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 50, 'referenced_works': ['https://openalex.org/W1440533077', 'https://openalex.org/W1517220382', 'https://openalex.org/W1527449606', 'https://openalex.org/W1671096165', 'https://openalex.org/W1966409247', 'https://openalex.org/W1973793594', 'https://openalex.org/W1984519656', 'https://openalex.org/W1985865997', 'https://openalex.org/W1988046726', 'https://openalex.org/W1988234478', 'https://openalex.org/W1998379637', 'https://openalex.org/W1999662503', 'https://openalex.org/W2004307428', 'https://openalex.org/W2005041653', 'https://openalex.org/W2013129122', 'https://openalex.org/W2014032103', 'https://openalex.org/W2015184499', 'https://openalex.org/W2017552085', 'https://openalex.org/W2025321862', 'https://openalex.org/W2027651584', 'https://openalex.org/W2032369191', 'https://openalex.org/W2037853818', 'https://openalex.org/W2038767330', 'https://openalex.org/W2058387186', 'https://openalex.org/W2059608682', 'https://openalex.org/W2064856371', 'https://openalex.org/W2070127123', 'https://openalex.org/W2089416282', 'https://openalex.org/W2090259345', 'https://openalex.org/W2091060269', 'https://openalex.org/W2092784030', 'https://openalex.org/W2093014736', 'https://openalex.org/W2093718194', 'https://openalex.org/W2093868716', 'https://openalex.org/W2121649258', 'https://openalex.org/W2122803878', 'https://openalex.org/W2172810566', 'https://openalex.org/W2317345293', 'https://openalex.org/W2951456638', 'https://openalex.org/W2952322094', 'https://openalex.org/W2953258647', 'https://openalex.org/W2953284619', 'https://openalex.org/W2983103512', 'https://openalex.org/W3004528772', 'https://openalex.org/W4205797238', 'https://openalex.org/W4242494532', 'https://openalex.org/W4243847624', 'https://openalex.org/W4298375532', 'https://openalex.org/W4302339329', 'https://openalex.org/W623063287'], 'related_works': ['https://openalex.org/W2952043064', 'https://openalex.org/W2169475757', 'https://openalex.org/W2123541348', 'https://openalex.org/W2097097278', 'https://openalex.org/W2094947119', 'https://openalex.org/W2054814387', 'https://openalex.org/W2049913996', 'https://openalex.org/W1990922246', 'https://openalex.org/W1973024351', 'https://openalex.org/W1713481988'], 'abstract_inverted_index': {'Abstract': [0], 'The': [1, 26, 85], 'aminolysis': [2, 155], 'reactions': [3], 'of': [4, 35, 41, 59, 87, 95, 107, 113, 143, 153], 'S': [5], '‐aryl': [6], 'N': [7], '‐arylthiocarbamates': [8], '(YC': [9], '6': [10, 14], 'H': [11, 15], '4': [12, 16], 'NH\uf8ffC(\uf8feO)\uf8ffSC': [13], 'Z,': [17], '1': [18], ')': [19], 'with': [20, 104, 133], 'anilines': [21, 149], 'in': [22, 48, 66, 77, 92], 'acetonitrile': [23], 'are': [24, 29, 91, 98, 130], 'studied.': [25], 'reaction': [27], 'rates': [28], 'more': [30], 'influenced': [31], 'by': [32], 'the': [33, 36, 39, 42, 46, 49, 55, 60, 67, 78, 88, 93, 108, 141, 144, 154], 'nucleophilicity': [34], 'nucleophile': [37, 79], 'than': [38, 76], 'nucleofugality': [40], 'leaving': [43, 68], 'group,': [44], 'but': [45], 'change': [47, 142], 'effective': [50], 'charge': [51], 'from': [52, 146, 157], 'reactants': [53], 'to': [54, 74, 148, 160], 'TS': [56], 'for': [57, 100], 'formation': [58, 106], 'tetrahedral': [61, 110], 'intermediate': [62], 'is': [63, 138], 'slightly': [64], 'greater': [65], 'group': [69], '(': [70, 80, 118, 123], 'β': [71, 81], 'Z': [72], 'from−0.07': [73], '−0.14)': [75], 'X': [82], '=': [83], '0.04–0.12).': [84], 'magnitude': [86], 'Brönsted': [89], 'coefficients': [90], 'range': [94], 'values': [96], 'that': [97, 140], 'consistent': [99, 132], 'a': [101, 134, 151, 158, 161], 'stepwise': [102, 135, 162], 'mechanism': [103, 156], 'rate‐limiting': [105], 'zwitterionic': [109], 'intermediate.': [111], 'Signs': [112], 'cross‐interaction': [114], 'constants,': [115], 'ρ': [116, 121, 127], 'XY': [117], '>': [119, 124], '0),': [120], 'XZ': [122], '0)': [125], 'and': [126], 'YZ': [128], '(<0),': [129], 'all': [131], 'mechanism.': [136], 'It': [137], 'concluded': [139], 'amine': [145], 'benzylamines': [147], 'causes': [150], 'shift': [152], 'concerted': [159], 'process.': [163], 'Copyright': [164], '©': [165], '2008': [166], 'John': [167], 'Wiley': [168], '&': [169], 'Sons,': [170], 'Ltd.': [171]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2097097278', 'counts_by_year': [{'year': 2015, 'cited_by_count': 1}, {'year': 2013, 'cited_by_count': 2}, {'year': 2012, 'cited_by_count': 5}], 'updated_date': '2024-09-09T01:06:21.648869', 'created_date': '2016-06-24'}