Title: ChemInform Abstract: Diastereo‐ and Enantioselective Intramolecular 1,6‐C—H Insertion Reactions of α‐Diazo Esters Catalyzed by Chiral Dirhodium(II) Carboxylates.
Abstract: Abstract The first catalytic asymmetric 1,6‐C—H insertion reaction of α‐diazo esters catalyzed by 1 mol % of a chiral Rh‐complex is developed which provides facile access to optically active oxygen‐containing six‐membered cyclic core structures of biologically active natural products and pharmaceutical agents.
Publication Year: 2015
Publication Date: 2015-06-25
Language: en
Type: article
Indexed In: ['crossref']
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